材料科学技术(英文版)2021,Vol.86Issue(27) :151-157.

A flexible nickel phthalocyanine resistive random access memory with multi-level data storage capability

Tariq Aziz Yun Sun Zu-Heng Wu Mustafa Haider Ting-Yu Qu Azim Khan Chao Zhen Qi Liu Hui-Ming Cheng Dong-Ming Sun
材料科学技术(英文版)2021,Vol.86Issue(27) :151-157.

A flexible nickel phthalocyanine resistive random access memory with multi-level data storage capability

Tariq Aziz 1Yun Sun 2Zu-Heng Wu 3Mustafa Haider 4Ting-Yu Qu 5Azim Khan 1Chao Zhen 2Qi Liu 6Hui-Ming Cheng 7Dong-Ming Sun2
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作者信息

  • 1. Shenyang National Laboratory for Materials Science,Institute of Metal Research,Chinese Academy of Sciences,72 Wenhua Road,Shenyang,110016,China;University of Chinese Academy of Sciences,19A Yuquan Road,Beijing,100049,China
  • 2. Shenyang National Laboratory for Materials Science,Institute of Metal Research,Chinese Academy of Sciences,72 Wenhua Road,Shenyang,110016,China;School of Material Science and Engineering,University of Science and Technology of China,72 Wenhua Road,Shenyang,110016,China
  • 3. Key Laboratory of Microelectronic Devices&Integrated Technology,Institute of Microelectronics,Chinese Academy of Sciences,3 Bei-Tu-Cheng West Road,Beijing,100029,China
  • 4. Shenyang National Laboratory for Materials Science,Institute of Metal Research,Chinese Academy of Sciences,72 Wenhua Road,Shenyang,110016,China;University of Chinese Academy of Sciences,19A Yuquan Road,Beijing,100049,China;Pak-Austria Fachhochschule:Institute of Applied Sciences and Technology,Mang,Khanpur Road,Haripur,KPK,Pakistan
  • 5. NUS Graduate School,Integrative Sciences and Engineering Programme,National University of Singapore,119077,Singapore
  • 6. Frontier Institute of Chip and System,Fudan University,2005 Songhu Road,Shanghai 200433,China
  • 7. Shenyang National Laboratory for Materials Science,Institute of Metal Research,Chinese Academy of Sciences,72 Wenhua Road,Shenyang,110016,China;School of Material Science and Engineering,University of Science and Technology of China,72 Wenhua Road,Shenyang,110016,China;Shenzhen Geim Graphene Center,Shenzhen International Graduate School,Tsinghua University,1001 Xueyuan Road,Shenzhen,518055,China
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Abstract

Metal phthalocyanine is considered one of the most promising candidates for the design and fabrication of flexible resistive random access memory(RRAM)devices due to its intrinsic flexibility and excel-lent functionality.However,performance degradation and the lack of multi-level capability,which can directly expand the storage capacity in one memory cell without sacrificing additional layout area,are the primary obstacles to the use of metal phthalocyanine RRAMs in information storage.Here,a flex-ible RRAM with pristine nickel phthalocyanine(NiPc)as the resistive layer is reported for multi-level data storage.Due to its high trap-concentration,the charge transport behavior of the device agrees well with classical space charge limited conduction controlled by traps,leading to an excellent performance,including a high on-off current ratio of 107,a long-term retention of 106 s,a reproducible endurance over 6000 cycles,long-term flexibility at a bending strain of 0.6%,a write speed of 50 ns under sequential bias pulses and the capability of multi-level data storage with reliable retention and uniformity.

Key words

Flexible/Metal phthalocyanine/Resistive random access memory/Multi-level

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基金项目

This work was supported by National Natural Science Founda-tion of China(Nos.61574143)

This work was supported by National Natural Science Founda-tion of China(61704175)

This work was supported by National Natural Science Founda-tion of China(51502304)

Strategic Priority Research Program of Chinese Academy of Sciences(Grant XDB30000000)

Key Research Program of Frontier Sci-ences of the Chinese Academy of Sciences(ZDBS-LY-JSC027)

Liaoning Revitalization Talents Program(XLYC1807109)

National Key Research and Development Program of China(2016YFB0401104)

出版年

2021
材料科学技术(英文版)
中国金属学会 中国材料研究学会 中国科学院金属研究所

材料科学技术(英文版)

CSTPCDCSCDSCI
影响因子:0.657
ISSN:1005-0302
参考文献量33
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