材料科学技术(英文版)2022,Vol.102Issue(7) :66-71.

Achievement of giant cryogenic refrigerant capacity in quinary rare-earths based high-entropy amorphous alloy

Yikun Zhang Jian Zhu Shuo Li Jiang Wang Zhongming Ren
材料科学技术(英文版)2022,Vol.102Issue(7) :66-71.

Achievement of giant cryogenic refrigerant capacity in quinary rare-earths based high-entropy amorphous alloy

Yikun Zhang 1Jian Zhu 1Shuo Li 1Jiang Wang 1Zhongming Ren1
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作者信息

  • 1. State Key Laboratory of Advanced Special Steels&Shanghai Key Laboratory of Advanced Ferrometallurgy&School of Materials Science and Engineering,Shanghai University,Shanghai 200444,China
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Abstract

Magnetic refrigeration(MR)by utilizing the magnetocaloric(MC)effect is recognized as one of the most potential promising solid state environmentally friendly and high efficiency alternative method to the well-used state-of-the-art gas compression cooling technique.In this work,a systematic investigation of quinary equi-atomic rare-earths(RE)based Er20Ho20Gd20Ni20Co20 high-entropy(HE)amorphous alloy in terms of the microstructure,magnetic and magnetocaloric(MC)properties have been reported.The Er20Ho20Gd20Ni20Co20 exhibits promising glass forming ability with an undercooled liquid region of 72 K.Excellent cryogenic MC performances can be found in wide temperature from~25 and~75 K,close to H2 and N2 liquefaction,respectively.Apart from the largest magnetic entropy change(-ΔSM)reaches 17.84 J/(kg K)with 0-7 T magnetic field change,corresponding refrigerant capacity(RC)attains a giant value of 1030 J/kg.The promising cryogenic MC performances together with the unique HE amorphous characterizations make the quinary Er20Ho20Gd20Ni20Co20 HE amorphous alloy attractive for cryogenic MR applications.

Key words

HE-amorphous ribbon/s Magnetocaloric performances/Rare earths/Magnetic properties/Giant refrigerant capacity

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基金项目

National Natural Sci-ence Foundation of China(52071197)

Science and Technol-ogy Committee of Shanghai Municipality(19ZR1418300)

Science and Technol-ogy Committee of Shanghai Municipality(19DZ2270200)

Independent Research and Development Project of State Key Laboratory of Advanced Special Steel,Shanghai Key Laboratory of Advanc(SKLASS2020-Z06)

出版年

2022
材料科学技术(英文版)
中国金属学会 中国材料研究学会 中国科学院金属研究所

材料科学技术(英文版)

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影响因子:0.657
ISSN:1005-0302
参考文献量56
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