材料科学技术(英文版)2022,Vol.111Issue(16) :88-98.

High temperature oxidation and ablation behaviors of HfB2-SiC/SiC coatings for carbon/carbon composites fabricated by dipping-carbonization assisted pack cementation

Lei Zhou Jiaping Zhang Dou Hu Qiangang Fu Wuqing Ding Jiaqi Hou Bing Liu Mingde Tong
材料科学技术(英文版)2022,Vol.111Issue(16) :88-98.

High temperature oxidation and ablation behaviors of HfB2-SiC/SiC coatings for carbon/carbon composites fabricated by dipping-carbonization assisted pack cementation

Lei Zhou 1Jiaping Zhang 1Dou Hu 1Qiangang Fu 1Wuqing Ding 1Jiaqi Hou 1Bing Liu 1Mingde Tong1
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作者信息

  • 1. State Key Laboratory of Solidification Processing,Shaanxi Key Laboratory of Fiber Reinforced Light Composite Materials,Northwestern Polytechnical University,Xi'an 710072,China
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Abstract

To improve the uniformity and the content of HfB2 in HfB2-Si-based ceramic coating and alleviate the damage of substrate,and then enhance the high-temperature(1700℃)oxidation and cyclic ablation resistances of carbon/carbon composites,a close-knit double layer HfB2-SiC/SiC coatings with a mosaic structure and high content of HfB2 were prepared by a novel dipping-carbonization assisted pack cemen-tation methods(DPC-HS/S).In contrast,a HfB2-SiC/SiC coatings were also fabricated by pack cementa-tion(PC-HS/S).Results revealed that the oxidation and ablation protective performances of the DPC-HS/S coatings were superior to those of PC-HS/S coatings.After 30 thermal cycles between 1500℃and room temperature,the mass gain of the coated sample was 0.78%,and the mass loss was 1.65%after oxidation at 1700℃for 156 h.Moreover,under an oxyacetylene torch ablation for 180 s(3 cycles),the linear abla-tion rate of the DPC-HS/S coated specimen was 1.62 um/s,which was much lower than that of PC-HS/S coated specimen(3.08μm/s).

Key words

C/C composites/HfB2/Oxidation resistance/Cyclic ablation resistance

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基金项目

国家自然科学基金(51872239)

国家自然科学基金(52061135102)

国家自然科学基金(52002321)

Creative Research Foundation of Science and Technology on Thermostructural Composite Materials Laboratory(5050200015)

Fundamental Research Funds for the Cen-tral Universities(G2020KY05125)

Xi'an Association for Science and Technology"Young Talent Support Project"(095920211338)

Analytical&Testing Center of Northwestern Polytechnical University(NWPU)()

出版年

2022
材料科学技术(英文版)
中国金属学会 中国材料研究学会 中国科学院金属研究所

材料科学技术(英文版)

CSTPCDCSCDSCI
影响因子:0.657
ISSN:1005-0302
参考文献量42
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