材料科学技术(英文版)2022，Vol.111Issue(16) ：189-203.

Remarkable catalysis of spinel ferrite XFe2O4(X=Ni,Co,Mn,Cu,Zn)nanoparticles on the dehydrogenation properties of LiAlH4:An experimental and theoretical study

Sheng Wei Jiaxi Liu Yongpeng Xia Huanzhi Zhang Riguang Cheng Lixian Sun Fen Xu Pengru Huang Federico Rosei Aleskey A.Pimerzin Hans Jüergen Seifert Hongge Pan
材料科学技术(英文版)2022，Vol.111Issue(16) ：189-203.
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Remarkable catalysis of spinel ferrite XFe2O4(X=Ni,Co,Mn,Cu,Zn)nanoparticles on the dehydrogenation properties of LiAlH4:An experimental and theoretical study

Sheng Wei 1Jiaxi Liu 2Yongpeng Xia 2Huanzhi Zhang 2Riguang Cheng 2Lixian Sun 1Fen Xu 2Pengru Huang 2Federico Rosei 3Aleskey A.Pimerzin 4Hans Jüergen Seifert 5Hongge Pan6
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作者信息

  • 1. School of Material Science&Engineering,Guangxi Key Laboratory of Information Materials and Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials,Guilin University of Electronic Technology,Guilin 541004,China;School of Mechanical&Electrical Engineering,Guilin University of Electronic Technology,Guilin 541004,China
  • 2. School of Material Science&Engineering,Guangxi Key Laboratory of Information Materials and Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials,Guilin University of Electronic Technology,Guilin 541004,China
  • 3. Centre énergie,Matériaux et Télécommunications,Institut National de la Recherche Scientifique,1650 Boul,Lionel Boulet,Varennes,J3×1S2,Quebec,Canada
  • 4. Samara State Technical University,Samara,443100,Russia
  • 5. Institute for Applied Materials,Karlsruhe Institute of Technology,Hermann von Helmholtz Platz 1,76344 Eggenstein Leopoldshafen,Germany
  • 6. School of New Energy Science and Technology,Xi'an Technological University,Xi'an 710021,China
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Abstract

Safe,compact,lightweight and cost-effective hydrogen storage is one of the main challenges that need to be addressed to effectively deploy the hydrogen economy.LiAlH4,as a solid-state hydrogen storage mate-rial,presents several advantages such as high hydrogen storage capacity,low price and abundant sources.Unfortunately,neither thermodynamic nor kinetic properties of dehydrogenation for LiAlH4 can fulfill the requirements of practical application.Thus,a series of spinel ferrite nanoparticles such as XFe2O4(X=Ni,Co,Mn,Cu,Zn,Fe)were prepared by using the modified thermal decomposition method,and then doped into LiAlH4 by using ball milling.Our results show that LiAlH4 doped with 7 wt％NiFe2O4 starts to release hydrogen at 69.1℃,and the total amount of hydrogen released is 7.29 wt％before 300℃.The activation energies of the two-step hydrogen release reactions of LiAlH4 doped with 7 wt％NiFe2O4 are 42.32 kJ mol-1 and 71.42 kJ mol-1,which are 59.0％and 63.6％lower than those of as-received LiAlH4,respec-tively.Combining the density functional theory(DFT)calculations,we reveal that both the presence of NiFe2O4 and in-situ formed Al4Ni3 in ball-milling decrease the desorption energy barrier of Al-H bonding in LiAlH4 and accelerate the breakdown of Al-H bonding through the interfacial charge transfer and the dehybridization of the Al-H cluster.Thus,the experimental and theoretical results open a new avenue toward designing high effective catalysts applied to LiAlH4 as a candidate for hydrogen storage.

Key words

Hydrogen storage/Lithium aluminum/Spinel ferrite nanoparticles

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基金项目

National Key Re-search and Development Program of China(2018YFB1502103)

National Key Re-search and Development Program of China(2018YFB1502105)

国家自然科学基金(U20A20237)

国家自然科学基金(51863005)

国家自然科学基金(51462006)

国家自然科学基金(51102230)

国家自然科学基金(52101245)

国家自然科学基金(51871065)

国家自然科学基金(51971068)

Scientific Research and Technology Development Program of Guangxi(AA19182014)

Scientific Research and Technology Development Program of Guangxi(AD17195073)

Scientific Research and Technology Development Program of Guangxi(AA17202030-1)

Scientific Research and Technology Development Program of Guangxi(AB21220027)

广西自然科学基金(2021GXNSFBA075057)

广西自然科学基金(2018GXNSFDA281051)

广西自然科学基金(2014GXNSFAA118401)

广西自然科学基金(2013GXNSFBA019244)

Guangxi Bagui Scholar Foundation()

Guangxi Collaborative Innovation centre of Structure and Property for New Energy and Materials()

Guangxi Advanced Functional Materials Foundation and Application Talents Small Highlands()

Chinesisch-Deutsche Kooperationsgruppe(GZ1528)

Study Abroad Program for Graduate Student of Guilin University of Electronic Technology(GDYX2019020)

Innovation Project of Guet Graduate Education(2020YCXS119)

Innovation Project of Guet Graduate Education(2019YCXS114)

Innovation Project of Guet Graduate Education(2018YJCX88)

出版年

2022
材料科学技术(英文版)
中国金属学会 中国材料研究学会 中国科学院金属研究所

材料科学技术(英文版)

CSTPCDCSCDSCI
影响因子：0.657
ISSN：1005-0302
参考文献量58
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