材料科学技术(英文版)2022，Vol.111Issue(16) ：287-297.

Tailoring of structural,optical and electrical properties of anatase TiO2 via doping of cobalt and nitrogen ions

Anchal Sharma Puneet Negi Ruhit Jyoti Konwar Hemaunt Kumar Yogita Verma Shailja Prakash Chandra Sati Bhargav Rajyaguru Himanshu Dadhich N.A.Shah P.S.Solanki
材料科学技术(英文版)2022，Vol.111Issue(16) ：287-297.
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Tailoring of structural,optical and electrical properties of anatase TiO2 via doping of cobalt and nitrogen ions

Anchal Sharma 1Puneet Negi 1Ruhit Jyoti Konwar 2Hemaunt Kumar 3Yogita Verma 1Shailja 1Prakash Chandra Sati 4Bhargav Rajyaguru 5Himanshu Dadhich 5N.A.Shah 5P.S.Solanki5
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作者信息

  • 1. Department of Physics,Eternal University,Baru Sahib,Himachal Pradesh,173101,India
  • 2. Centre of Excellence in Energy Science and Technology,Shoolini University,Solan,Himachal Pradesh,173229,India
  • 3. Department of Applied Science and Humanities,Rajkiya Engineering College,Bijnor,Uttar Pradesh,246725,India
  • 4. Department of Physics,Rajiv Gandhi Government Post Graduate College,Mandsaur,Madhya Pradesh,458001,India
  • 5. Department of Physics,Saurashtra University,Rajkot,360005,India
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Abstract

Pure(pristine)anatase and mono-doped and co-doped derivatives of TiO2 having nitrogen(N)and cobalt(Co)as dopants with respective fixed doping concentrations of 0.7 mol.％and 1.0 mol.％were synthesized using auto-combustion sol-gel technique.The doping effects at corresponding non-metal and transition metal sites of TiO2 on the basis of the structural,optical and electrical properties have been investi-gated.X-ray diffraction(XRD)measurement confirms the formation of pure anatase phase of TiO2 for all samples having 141/amd space group of tetragonal structure which has been also verified by the Raman spectroscopy measurement.Various crystallographic parameters have been calculated by performing Ri-etveld refinement of XRD data including average crystallite size that has been observed in the range of 10-15 nm.Pure anatase phase indicates the incorporation of Co2+into TiO2 lattice which assists the sub-stitution of N in place of oxygen in co-doped TiO2.The band gap tuning towards the visible region from 3.2 to 2.1 eV has been achieved with mono-doping and co-doping of the N and Co in TiO2 lattice.This can be described in terms of the formation of localized levels of N-2p and Co-3d states in mono-doping and an isolated intermediate band formation in co-doping case.Electrical properties have been inves-tigated in details and explained as the synergetic effects of structural and inherent ionic characters of various dopants.The observed band gaps of all doped samples lie within the visible region which makes them pertinent as the solar energy harnessing materials for photocatalytic and photovoltaic applications.

Key words

TiO2/Sol-Gel/X-ray diffraction/Electrical properties/Optical properties

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基金项目

AMRC of IIT Mandi,Hi-machal Pradesh,India for providing Raman Spectroscopy facility()

出版年

2022
材料科学技术(英文版)
中国金属学会 中国材料研究学会 中国科学院金属研究所

材料科学技术(英文版)

CSTPCDCSCDSCI
影响因子：0.657
ISSN：1005-0302
参考文献量71
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