材料科学技术(英文版)2022,Vol.128Issue(33) :148-159.

Core-shell structured Co@NC@MoS2 magnetic hierarchical nanotubes:Preparation and microwave absorbing properties

Yunfei Zhang Yulong Li Mengmeng Wei Dengtao Yang Qiuyu Zhang Baoliang Zhang
材料科学技术(英文版)2022,Vol.128Issue(33) :148-159.

Core-shell structured Co@NC@MoS2 magnetic hierarchical nanotubes:Preparation and microwave absorbing properties

Yunfei Zhang 1Yulong Li 2Mengmeng Wei 2Dengtao Yang 2Qiuyu Zhang 1Baoliang Zhang3
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作者信息

  • 1. School of Chemistry and Chemical Engineering,Northwestern Polytechnical University,Xi'an 710072,China;Xi'an Key Laboratory of Functional Organic Porous Materials,Northwestern Polytechnical University,Xi'an 710129,China
  • 2. School of Chemistry and Chemical Engineering,Northwestern Polytechnical University,Xi'an 710072,China
  • 3. School of Chemistry and Chemical Engineering,Northwestern Polytechnical University,Xi'an 710072,China;Shaanxi Engineering and Research Center for Functional Polymers on Adsorption and Separation,Sunresins New Materials Co.Ltd.,Xi'an 710072,China
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Abstract

In this study,a new lightweight one-dimensional absorber Co@NC@MoS2 was designed and prepared.Firstly,polydopamine(PDA)was coated by oxidative self-polymerization with cobalt-nitrilotriacetic acid chelate nanowires(Co-NTAC)as template.Then core-shell structured magnetic hierarchical nanotubes(Co@PDA@MoS2)were prepared by one-step hydrothermal method.After thermal annealing,PDA layer was transformed into nitrogen doped carbon layer(NC)to obtain the efficient microwave absorber Co@NC@MoS2.The removal of template and growth of MoS2 were completed simultaneously,the prepa-ration process was simplified.Because of its good magnetic loss and dielectric loss,Co@NC@MoS2 shows excellent microwave absorption performance.Under filler content of 15 wt.%,the minimum reflection loss(RLmin)can reach-61.97 dB@9.2 GHz,and the effective absorption bandwidth(EAB)is 5.6 GHz.The elec-tromagnetic parameters of Co@NC@MoS2 can be further adjusted by changing the load of MoS2.Mean-while,the structure and composition of Co@NC@MoS2 were systematically analyzed.The influence of the microstructure on the microwave absorbing properties was investigated,and the microwave attenuation mechanism is revealed.As an efficient and lightweight absorber,Co@NC@MoS2 has potential application value in the construction of new stealth coatings.

Key words

Nanotubes/Magnetic materials/Core-shell structure/MoS2 nanosheets/Electromagnetic wave absorption

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基金项目

国家自然科学基金(21975206)

Analytical&Testing Center of Northwestern Polytechnical University for SEM and TEM characterizations()

出版年

2022
材料科学技术(英文版)
中国金属学会 中国材料研究学会 中国科学院金属研究所

材料科学技术(英文版)

CSTPCDCSCDSCI
影响因子:0.657
ISSN:1005-0302
被引量1
参考文献量50
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