材料科学技术(英文版)2022,Vol.129Issue(34) :15-26.

Heterostructure design of MOFs derived Co9S8/FeCoS2/C composite with efficient microwave absorption and waterproof functions

Runrun Cheng Yan Wang Xiaochuang Di Zhao Lu Ping Wang Xinming Wu
材料科学技术(英文版)2022,Vol.129Issue(34) :15-26.

Heterostructure design of MOFs derived Co9S8/FeCoS2/C composite with efficient microwave absorption and waterproof functions

Runrun Cheng 1Yan Wang 1Xiaochuang Di 1Zhao Lu 1Ping Wang 1Xinming Wu1
扫码查看

作者信息

  • 1. School of Materials and Chemical Engineering,Xi'an Technological University,Xi'an 710021,China
  • 折叠

Abstract

At present,the problem of electromagnetic wave(EMW)pollution is critical,and the design of high-performance absorbers is of great significance.Based on the synergy between dielectric and magnetic losses,and between multicomponents in heterostructures,the development of light-weight absorbers with a strong absorption capability and multiple scattering is a promising strategy to achieve high-performance absorbers.In this work,CoFe-MOF precursors with a bouquet-like structure were prepared via the hydrothermal method,and Co7Fe3/C and Co9S8/Fe/CoS2/C composites were obtained through a carbonization and sulfuration treatment during the high-temperature pyrolysis process,respectively.The experimental and theoretical results show that the Co9S8/FeCoS2/C composite has a better EMW absorp-tion performance,and its optimal reflection loss(RL)value is-53.9 dB at a low filler loading of 20 wt.%,which is due to the S doping that enhances the interface polarization relaxation process and improves the impedance matching characteristics.Moreover,the Co9S8/FeCoS2/C composite can be as candidates of high-efficiency absorbers in extreme application environments.

Key words

Electromagnetic absorption/Metal-organic frameworks(MOFs)/Bouquet-like CoFe-MOF/Sulfur doping

引用本文复制引用

基金项目

国家自然科学基金(61701386)

国家自然科学基金(21975196)

Young Star Project of Science and Technology of Shaanxi Province(2019KJXX-033)

Youth Innovation Team of Shaanxi Universities()

出版年

2022
材料科学技术(英文版)
中国金属学会 中国材料研究学会 中国科学院金属研究所

材料科学技术(英文版)

CSTPCDCSCDSCI
影响因子:0.657
ISSN:1005-0302
参考文献量72
段落导航相关论文