Abstract
Herein,a low-cost,biodegradable,and high-performance microwave shielding graphite/starch mate-rial was fabricated via constructing a cation-π interaction between ammonium ions and graphite.The graphite flakes and starch were firstly mixed with distilled water containing ammonium hydroxide to form graphite/starch slurry under an ultrasonic assistant.The cation-π interaction could improve delam-ination degree and dispersion of graphite in starch matrix.The slurry was first used as a coating material on the surface of wood and paper to develop shielding packages.The effect of coating thickness and coating layers on EM shielding property of the materials was investigated.Second,the composites with a high orientation of graphite were fabricated by compression at high pressures.The electrical conductivity and EM shielding effectiveness(SET)of the materials were greatly enhanced by construction of cation-πinteraction and orientation of graphite.Specifically,the EM SET values increased from 56.9 to 66.8 dB for the composites with 50 wt.％graphite and 2.0 mm in thickness by constructing cation-π interaction.The EM SET values raised from 17.4 to 66.8 dB via the graphite orientation in the materials with the same components and thickness.The shielding mechanism of the compressed composites with orientation dis-persion of graphite was also discussed in comparison to the coating layer with random dispersion of graphite.
基金项目
国家自然科学基金(52173264)
重庆市自然科学基金(cstc2020jcyjmsxmX0401)
NETL
NSTL
万方数据