Abstract
P-type Mg3Sb2-based Zintls have attracted considerable interest in the thermoelectric(TE)field due to their environmental friendliness and low cost.However,compared to their n-type counterparts,they show relatively low TE performance,limiting their application in TE devices.In this work,we simul-taneously introduce Bi alloying at Sb sites and Ag doping at Mg sites into the Mg3Sb2 to coopera-tively optimize the electrical and thermal properties for the first time,acquiring the highest ZT value of～0.85 at 723 K and a high average ZT of 0.39 in the temperature range of 323-723 K in sample Mg2.94Ag0.06Sb1.9Bi0.1.The first-principle calculations show that the co-doping of Ag and Bi can shift the Fermi level into the valence band and narrow the band gap,resulting in the increased carrier concentration from 3.50 × 1017 cm-3 in the reference Mg3Sb0.9Bi01 to～7.88 × 1019 cm-3 in sample Mg2.94Ag0.06Sb0.9Bi0.1.As a result,a remarkable power factor of～778.9 μW m-1 K-2 at 723 K is achieved in sample Mg2.94Ag0.06Sb0.9Bi0.1.Meanwhile,a low lattice thermal conductivity of～0.48 Wm-1 K-1 at 723 K is also obtained with the help of phonon scattering at the distorted lattice,point defects,and nano-precipitates in sample Mg2.94Ag0.06Sb0.9Bi0.1.The synergistic effect of using the multi-element co-doping/-alloying to optimize electrical properties in Mg3Sb2 holds promise for further improving the TE performance of Zintl phase materials or even others.
基金项目
国家自然科学基金(U21A2054)
国家自然科学基金(52273285)
国家自然科学基金(52061009)
国家自然科学基金(52262032)
国家重点研发计划(2022YFE0119100)
Guangxi Science and Technology Planning Project(AD21220056)
NETL
NSTL
万方数据