首页|Bi2WO6/AgInS2 S-scheme heterojunction:Efficient photodegradation of organic pollutant and toxicity evaluation
Bi2WO6/AgInS2 S-scheme heterojunction:Efficient photodegradation of organic pollutant and toxicity evaluation
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Constructing of heterojunction was identified as a feasible way to improve photocatalytic activity of pho-tocatalyst.In this work,a n-p type Bi2WO6/AgInS2 S-scheme heterojunction was successfully prepared for organic pollutants degradation.This Bi2WO6/AgInS2 S-scheme heterojunction exhibited much higher pho-tocatalytic activity towards Rhodamine B(92.24%,expose to visible light for 60 min),norfloxacin(81.73%,expose to visible light for 90 min)and levofloxacin(87.46%,expose to visible light for 90 min)than pure Bi2WO6 and pure AgInS2.Toxicity analysis indicated the low environmental toxicity of Rhodamine B degradation intermediates for Rye seeds and Sudangrass seeds germination and growth.Mechanism study displayed that AgInS2 and Bi2WO6 work as the primary photocatalyst to form·O2-and ·OH,respectively.The improved photocatalytic activity of the Bi2WO6/AgInS2 S-scheme heterojunction was due to the im-proved light response range and intensified carrier separation capability.Additionally,a S-scheme charge transfer mechanism including multiple charge transfer channels was proposed.This work could provide an effective strategy for organic pollutants degradation in wastewater.