首页|Multifunctional 3D electrodes for tunable high-performance hybrid zinc batteries

Multifunctional 3D electrodes for tunable high-performance hybrid zinc batteries

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The high energy density and long cycling life of zinc-based batteries are restricted by the single electro-chemical reaction system.To improve the electrochemical performance of batteries,electrode materials,electrolytes and membranes are regularly modified,while the construction of battery systems is often ne-glected.Herein,a multifunctional electrode was prepared via 3D printing,which successfully coupled the metal oxide/hydroxide-zinc battery(MZB)reaction and rechargeable zinc-air battery(RZAB)reaction.The ultrathick hierarchical 3D electrode provided a tunable capacity for the MZB system,which enabled the possibility for feasible output regulation of this hybrid system.The active material NiCoLDH was discov-ered to undergo structure reconstruction during cycling,which revealed the capacity fading mechanism.The delicate system design and discovery ensured a high-performance battery configuration and revealed the corresponding mechanism,opening a new avenue for developing high-performance zinc batteries.

Zinc batteryMultifunctional electrode3D printingHierarchical 3D structure

Yiming Chen、Minxuan Zhou、Junpeng Wu、Xidan Xiao、Lin Xu

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School of Chemistry and Materials Science,Hubei Engineering University,Xiaogan 432000,China

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China

National Natural Science Foundation of ChinaNational Key Research and Development Program of ChinaKey Research and Development Program of Hubei Provinceindependent Innovation Projects of the Hubei Longzhong LaboratorySanya Science and Education Innovation Park of Wuhan University of Technology

522722342020YFA07150002021BAA0702022ZZ-202021KF0011

2024

材料科学技术(英文版)
中国金属学会 中国材料研究学会 中国科学院金属研究所

材料科学技术(英文版)

CSTPCD
影响因子:0.657
ISSN:1005-0302
年,卷(期):2024.178(11)
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