材料科学技术(英文版)2024,Vol.181Issue(14) :138-151.DOI:10.1016/j.jmst.2023.08.068

Achieving ultra-high corrosion-resistant Mg-Zn-Sc alloys by forming Sc-assisted protective corrosion product film

Wenjun Ci Xianhua Chen Xu Dai Chunquan Liu Yanlong Ma Di Zhao Fusheng Pan
材料科学技术(英文版)2024,Vol.181Issue(14) :138-151.DOI:10.1016/j.jmst.2023.08.068

Achieving ultra-high corrosion-resistant Mg-Zn-Sc alloys by forming Sc-assisted protective corrosion product film

Wenjun Ci 1Xianhua Chen 1Xu Dai 2Chunquan Liu 1Yanlong Ma 3Di Zhao 4Fusheng Pan1
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作者信息

  • 1. College of Materials Science and Engineering,Chongqing University,Chongqing 400045,China;National Engineering Research Center for Magnesium Alloys,Chongqing University,Chongqing 400045,China
  • 2. State Key Laboratory of Power Transmission Equipment & System Security and New Technology,Chongqing University,Chongqing 400044,China
  • 3. College of Materials Science and Engineering,Chongqing University of Technology,Chongqing 400054,China
  • 4. School of Mechanical Engineering,Suzhou University of Science and Technology,Suzhou 215009,China
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Abstract

The weak corrosion resistance of magnesium and its alloys greatly limited the industrial application.Though functional self-healing coatings have been proposed as countermeasures,repeated damages on coatings under practical installation and complex external environments could require self-adaptive cor-rosion protection against multiple abrasions.In this study,an ultra-high corrosion-resistant Mg-1Zn-1Sc(wt.%)alloy with a corrosion rate of 0.087 mm/y has been designed and prepared,which has fine grains and uniform structure of a nano-scale ScZn phase with low potential.A unique and dense corrosion prod-uct film with a three-layered structure was found and studied on Mg-1Zn-1Sc alloy,providing excellent corrosion protection.In addition,the formation and protection mechanisms of the three-layered corrosion product film on Mg-1Zn-1Sc alloy have been discussed and proposed.The growth behavior of protective corrosion product film could be driven by the synergy of Sc and Zn elements.Furthermore,with the in-crease of Sc content,the strength,plasticity,and corrosion resistance of Mg-1Zn-xSc(x=0,0.2,0.6,1.0,in wt.%)alloys increased simultaneously.The high corrosion resistance and moderate mechanical perfor-mance qualify Mg-1Zn-1Sc alloy as a promising candidate for diverse industrial applications.

Key words

High corrosion resistance/Mechanical performance/Mg-Zn-Sc alloy/Corrosion product film/Three-layer structure/SKPFM

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基金项目

国家自然科学基金(52225101)

国家自然科学基金(52171103)

国家重点研发计划(2021YFB3701100)

Guangdong Major Project of Basic and Applied Basic Research(2020B0301030006)

中央高校基本科研业务费专项(2020CDJDPT001)

出版年

2024
材料科学技术(英文版)
中国金属学会 中国材料研究学会 中国科学院金属研究所

材料科学技术(英文版)

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影响因子:0.657
ISSN:1005-0302
参考文献量74
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