Abstract
Hybrid engineering is gradually deemed as a powerful approach to solving the bottleneck problem of metal-organic framework(MOF)derived absorbers for practical application.Herein,a new type of semiconductor/carbon-based hybrid material was successfully prepared by phytic acid(PA)modification and carbonization of MOF/bacterial cellulose(BC)precursors,which remedied the drawbacks of struc-tural instability,lethal byproducts and complicated steps reported previously.Specifically,the obtained Fe(PO3)2@C/phosphorus-doped carbon foam(Fe(PO3)2@C/PCF)had a 3D hybrid micro-nanostructure that integrated spatial microcurrent network,multi-level pores,heterogeneous interfaces and lattice defects,showing its unique advantages of low filler content(15 wt.％),moderate surface reflectivity,multi-band microwave absorption and radar stealth.The experimental analysis and CST simulation further revealed that PA dosage can precisely adjust the hybrid phase content,pore texture and electromagnetic param-eters of the final product to achieve synergistic enhancement of multiple dielectric response,impedance matching and attenuation capacity.As a result,an effective bandwidth(EAB)of 6 GHz and a minimum reflection loss(RLmin)of-57.0 dB were obtained in the Ku-and C-bands,respectively.These encourag-ing results may advance the development of novel MOF-derived absorbents based on the hybridization principle.
基金项目
National Key Research and Development Program of China(2019YFE0122900)
National Natural Science Foundation of China(52373303)
Program of Shanghai Technology Research Leader(18XD1423800)
NETL
NSTL
万方数据