首页|Free-standing BiOI@MWCNTs photoelectrodes for photo-rechargeable zinc-ion batteries
Free-standing BiOI@MWCNTs photoelectrodes for photo-rechargeable zinc-ion batteries
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Photo-rechargeable batteries can implement solar energy harvesting and storage simultaneously and have attracted strong interest from researchers.The development of photoactive electrodes is the key to pro-moting the development of high-performance photocells.Herein,a free-standing BiOI@MWCNTs film is developed as photoelectrode to achieve the effective separation of photogenerated electron-hole pairs for high-efficiency solar-electric-chemical energy conversion.Light can charge up photocells with a photo-conversion efficiency of~1.3%,as well as accelerate charge transfer without requiring any external bias voltage.Ex situ XRD and XPS tests prove that the enhanced electrochemical reaction kinetics can improve the chemical-electric energy conversion efficiency under illumination.The capacity of the proposed pho-tocell can be increased by 10.6%(from 195 mA h g-1 to 216 mA h g-1 at 0.2 A g-1)and 57.9%(from 76 mA h g-1 to 120 mA h g-1at 5.0 A g-1)in light condition,while exhibiting a cyclic life of up to 600 cycles.This work can help to deepen the understanding of photo-rechargeable batteries.
Free-standing BiOI@MWCNTs filmPhotoactive electrodePhotoaccelerated chemical-electric energy conversionLong cyclic lifePhoto-rechargeable zinc ion battery
Bei Long、Xiaojie Liang、Yong Pei、Xiongwei Wu、Xianyou Wang、Man-Kay Law
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State Key Laboratory of Analog and Mixed-Signal VLSI,University of Macau,Macau 999078,China
School of Chemistry,Xiangtan University,Xiangtan 411105,China
School of Chemistry and Materials Science,Hunan Agricultural University,Changsha 410128,China