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微生物矿化技术提升钢渣水泥基材料的抗压强度与安定性

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基于微生物矿化技术来提升钢渣胶凝材料的抗压强度和安定性。通过研究微生物掺入后对于钢渣胶凝材料抗压强度和线性膨胀率的影响,并利用全自动压汞仪(MIP)、场发射扫描电子显微镜(SEM)和X射线衍射仪(XRD)分析了砂浆试件的孔隙率、微观形貌和物相组成,对微生物改性钢渣胶凝材料的机理进行了探讨。研究结果表明,微生物芽孢的最佳添加量为水泥和钢渣总质量的2。0%;微生物可以促使钢渣胶凝材料中Ca(OH)2,游离CaO和游离MgO生成碳酸盐沉淀,降低基体中的孔隙率,提高其抗压强度;加入微生物后钢渣胶凝材料的抗压强度高达40。8 MPa,但线性膨胀率仅为0。45‰。在钢渣胶凝材料理化环境下,微生物芽孢可萌发生长成细胞营养体,在碳酸酐酶的作用下,可以有效降低钢渣胶凝材料中的游离CaO和游离MgO的含量,从而提高其安定性。
Improving the Compressive Strength and Stability of Steel Slag Cement-based Materials by Microbial Mineralization Technology
Using the microbial mineralization technology to improve the compressive strength and stability of steel slag cementitious materials was studied.The effect of microorganism on the compressive strength and linear expansion rate of steel slag cement-based material was studied,and the porosity,micro morphology and phase composition of mortar specimens were analyzed by automatic mercury porosimeter (MIP),field emission scanning electron microscope (SEM) and X-ray diffraction (XRD).The microbial modification mechanism of steel slag cement-based material was discussed in detail.The experiment test results showed that the optiaml addition amount of microbial spore was 2.0% of the total mass of cement and steel slag.Microorganisms could promote the formation of carbonate precipitation of Ca(OH)2,free CaO and free MgO in steel slag cement-based material,reduce the porosity in the matrix and improve the compressive strength.The compressive strength of the steel slag cement-based material after adding microorganism was as high as 40.8 MPa,while the linear expansion rate was only 0.45‰.In the physical and chemical environment of steel slag cement-based material,microbial spores could germinate and grow into vegetative cells.Under the action of carbonic anhydrase,the content of free CaO and free MgO in steel slag cement-based material could be effectively reduced,so as to improve the stability.

SlagMicroorganismCementCompressive strengthStability

黄湘寒、肖楮文、梁永欣、张娜

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梧州职业学院建筑环保工程学院,广西梧州 543002

中南大学物理与电子学院,湖南长沙 410083

柳州工学院土木建筑工程学院,广西柳州 545616

钢渣 微生物 水泥 抗压强度 安定性

国家自然科学基金项目广西高校中青年教师科研基础能力提升项目

520780792020KY60017

2024

材料科学与工程学报
浙江大学

材料科学与工程学报

CSTPCD北大核心
影响因子:0.765
ISSN:1673-2812
年,卷(期):2024.42(4)