首页|纳米限域材料的制备及其在污染治理中的应用研究进展

纳米限域材料的制备及其在污染治理中的应用研究进展

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纳米技术在环境污染治理中具有广泛前景,然而其在应用过程中存在纳米颗粒及活性中心易团聚失活的问题.将纳米粒子的活性中心限制在载体的孔道内,构建出新型纳米限域材料可以有效克服这一缺点.同时,凭借材料的纳米限域效应,一定程度上可影响水的氢键网络结构,并会影响反应中中间活性粒子的演化、传质速率、晶体的生长和成核阶段过程,以及提高局部空间内反应底物的浓度.本文系统梳理了纳米限域材料的制备方法,并对比分析了各种制备方法的优缺点,归纳总结了近年来纳米限域材料在吸附和高级氧化降解污染物中的研究进展,展望了未来纳米限域材料在环境污染物治理领域的研发及应用前景.
Research progress on the preparation of nano-confined materials and their application in the treatment of environmental pollution
Nanotechnology holds great promise in environmental pollution control.However,nanoparticles and active centers are prone to agglomerate and deactivate in the process of application.By confining the active center of nanoparticles to the pore of the carrier,a new type of nano-confined material can overcome this shortcoming effectively.Meanwhile,with the nano-confined effect of the material,the hydrogen bond network structure of water can be influenced to some extent,as well as the evolution of intermediate particles in the reaction,mass transfer rates,crystal growth and nucleation stage process.Moreover,the concentration of the reaction substrate in the local space can also be improved by the material.Therefore,this paper systematically reviews the preparation methods of nano-confined materials and compares the advantages and disadvantages of these methods.In addition,the research progress of nano-confined materials in the adsorption and advanced oxidative degradation of pollutants in recent years is concluded.Last but not least,this paper looks into future research and application of nano-confined materials in the field of environmental pollutant treatment.

nanoconfinement effectsmaterials preparationcatalytic degradationefficient adsorptionpollution control

程美娜、陈燚钧、刘锋、李娟红、杨海亮、刘忻

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苏州科技大学环境科学与工程学院环保应用技术研究所,江苏苏州 215009

苏州科技大学水处理技术与材料协同创新中心,江苏苏州 215009

常州工程职业技术学院检验检测认证学院,江苏常州 213164

苏州科特环保股份有限公司,江苏苏州 215164

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纳米限域效应 材料制备 催化降解 高效吸附 污染治理

常州市科技支撑计划项目难降解工业废水低碳处理技术研发项目江苏省研究生科研与实践创新计划项目江苏省研究生科研与实践创新计划项目江苏省高校水处理技术与材料协同创新中心预研课题

CE20212024352211266SJCX22_1554KYCX22_3298XTCXSZ2022-8

2024

10.11951/j.issn.1005-0299.20230023

材料科学与工艺
中国材料研究学会 哈尔滨工业大学

材料科学与工艺

CSTPCD北大核心
影响因子：0.491
ISSN：1005-0299
年,卷(期)：2024.32(2)
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