首页|热压烧结新型WC/Al0.5CoCrFeNiTi0.5硬质合金摩擦磨损性能研究

热压烧结新型WC/Al0.5CoCrFeNiTi0.5硬质合金摩擦磨损性能研究

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为抑制传统WC硬质合金在烧结制备过程中的晶粒长大,提高其使用寿命,本文以Al0.5CoCrFeNiTi0.5高熵合金为粘结剂,在不添加晶粒生长抑制剂的前提下,采用热压烧结工艺制备了粘结剂含量分别为17wt.%、20wt.%和25wt.%的WC/Al0.5CoCrFeNiTi0.5的新型硬质合金,并以相同工艺制备WC/20wt.%Co作为对照样品.研究了 WC/Al0.5 CoCrFeNiTi0.5新型硬质合金的微观组织、力学性能,及其在室温和800 ℃高温条件下的摩擦磨损性能.研究结果表明,在不添加晶粒生长抑制的条件下,以 Al0.5CoCrFeNiTi0.5为粘结剂可以获得超细晶 WC/Al0.5CoCrFeNiTi0.5硬质合金.WC/20wt.%Al0.5CoCrFeNiTi0.5硬质合金具有最好的综合力学性能,其硬度和断裂韧性分别为(2 389±12)HV30和(15.95±0.5)MPa.m1/2,均优于相同工艺制备的WC/20wt.%Co硬质合金.在室温下,WC/17wt.%Al0.5CoCrFeNiTi0.5硬质合金磨损率最小,耐磨性能最好.随着粘结剂含量增加,耐磨性能逐渐降低.WC/Al0.5CoCrFeNiTi0.5硬质合金在室温下的磨损机理主要为磨粒磨损.在800℃高温条件下,WC/20wt.%Al0.5CoCrFeNiTi0.5硬质合金磨损率最小,磨损机理为磨粒磨损、氧化磨损和粘着磨损.在室温和800 ℃以下,WC/Al0.5CoCrFeNiTi0.5硬质合金的磨损率均低于相同工艺制备的WC/20Co硬质合金.
Research on friction and wear properties of novel WC/Al0.5CoCrFeNiTi0.5 cemented carbide fabricated by hot pressing sintering
To suppress the grain growth of traditional WC har alloys during the sintering process and improve their service life,this study used Al0.5CoCrFeNiTi0.5 high-entropy alloy as the binder to fabricate a novel WC/Al0.5CoCrFeNiTi0.5 cemented carbide with binder contents of 17wt.%,20wt.%and 25wt.%through hot pressing sintering without adding grain growth inhibitors.WC/20wt.%Co was prepared using the same process as a control sample.The microstructure,mechanical properties,and friction and wear properties at room temperature and 800 ℃ were studied.The results show that ultrafine grain WC/Al0.5CoCrFeNiTi0.5 cemented carbide can be obtained by using Al0.5CoCrFeNiTi0.5 as binder without adding grain growth inhibitiors.WC/20wt.%Al0.5CoCrFeNiTi0.5 cemented carbide exhibits the best comprehensive mechanical properties,with a hardness of(2 389±12)HV30 and a fracture toughness of(15.95±0.5)MPa·m12,both superior to WC/20wt.%Co cemented carbide prepared by the same process.At room temperature,WC/17wt.%Al0.5CoCrFeNiTi0.5 cemented carbide shows the lowest wear rate and the best wear resistance.As the binder content increases,the wear resistance gradually decreases.The wear mechanism of WC/Al0.5CoCrFeNiTi0.5 cemented carbide at room temperature is mainly abrasive wear.Under the high temperature condition of 800 ℃,WC/20wt.%Al0.5CoCrFeNiTi0.5 cemented carbide exhibits the lowest wear rate,with wear mechanism including abrasive wear,oxidation wear and adhesive wear.Moreover,at room temperature and below 800 ℃,the wear rate of WC/Al0.5CoCrFeNiTi0.5 cemented carbide is lower than that of WC/20wt.%Co cemented carbide prepared by the same process.

cemented carbidehigh entropy alloy bindermechanical propertiesfriction wearwear rate

何攀、王文、强凤鸣、张莹、乔柯、王快社

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西安建筑科技大学冶金工程学院功能材料加工国家地方联合工程研究中心,西安 710055

硬质合金 高熵合金粘结剂 力学性能 摩擦磨损 磨损率

2024

材料科学与工艺
中国材料研究学会 哈尔滨工业大学

材料科学与工艺

CSTPCD北大核心
影响因子:0.491
ISSN:1005-0299
年,卷(期):2024.32(6)