首页|聚醚砜多孔纤维网纱层间增韧碳纤维/环氧复合材料的性能

聚醚砜多孔纤维网纱层间增韧碳纤维/环氧复合材料的性能

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先用湿法纺丝制备聚醚砜(PES)多孔纤维并进行湿法抄造制备出四种不同面密度的PES多孔纤维网纱(PESV),用真空辅助树脂灌注成型(VARI)制备出聚醚砜多孔纤维网纱层间增韧碳纤维/环氧复合材料.研究了PES多孔纤维在环氧树脂的溶解行为以及复合材料的I型层间断裂韧性(GⅠC)和II型层间断裂韧性(GⅡC)、层间剪切强度和弯曲性能,并分析了复合材料层间断裂的微观形貌.结果表明,固化温度为180℃时,PES多孔纤维完全溶解在环氧树脂中;PESV面密度为31.6g/m2时CF/EP复合材料的GⅠC和GⅡC最佳,分别提高了54.4%和62.2%.其原因是,PES多孔纤维在环氧树脂中溶解后相分离形成了 PES/环氧树脂的两相结构,改善了层间韧性;PESV面密度为21.9 g/m2时,复合材料的层间剪切强度、弯曲强度和弯曲模量也分别提高了2.9%、4.0%和7.7%.
Performance of Interlayer Toughened Carbon Fiber/Epoxy Composites of Polyethersulfone Porous Fiber Veil
In order to improve the interlaminar toughness of carbon fiber/epoxy(CF/EP)composites,polyethersulfone(PES)porous fibers were prepared by wet spinning,and four PES porous fiber veils(PESV)with different areal densities were prepared by wet-laid method,which were subsequently used for interlaminar toughening of CF/EP composites by vacuum-assisted resin infusion molding(VARI).The dissolution behavior of PES porous fibers in epoxy resin,the mode Ⅰ(GⅠC)and mode Ⅱ(GⅡC)interlaminar fracture toughness,the interlaminar shear strength and flexural properties of the composites were sys-tematically examined,and the interlaminar fracture microscopic morphology of the composites was also characterized.The results showed that the PES porous fibers were completely dissolved in the epoxy res-in at the curing temperature of 180℃;The GⅠC and GⅡC of CF/EP composites were best at the areal densi-ty of 31.6 g/m2,which increased by 54.4%and 62.2%,respectively,which may be ascribed to that the phase separation of PES porous fibers dissolved in epoxy resin resulted in a two-phase PES/epoxy struc-ture,thereby,improved the interlayer toughness;The interlaminar shear strength,flexural strength and flexural modulus of CF/EP composites also increased by 2.9%,4.0%and 7.7%,respectively,for the areal density of 21.9 g/m2.

compositecarbon fiberinterlaminar toughenpolyethersulfonefiber veil

李朝阳、薛怿、阳泽濠、赵庆志、彭砚双、刘勇、杨建平、张辉

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东华大学材料科学与工程学院纤维材料改性国家重点实验室 上海 201620

东华大学民用航空复合材料协同创新中心 上海 201620

复合材料 层间增韧 碳纤维 聚醚砜 纤维网纱

上海市科委"科技创新行动计划"国家重点研发计划

205111073002022YFB3709202

2024

材料研究学报
国家自然科学基金委员会 中国材料研究学会

材料研究学报

CSTPCD北大核心
影响因子:0.605
ISSN:1005-3093
年,卷(期):2024.38(1)
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