材料研究学报2024,Vol.38Issue(1) :51-60.DOI:10.11901/1005.3093.2022.647

BNZ组分对KNN基无铅压电陶瓷结构和性能的影响

Effect of BNZ Component on Structure and Property of KNN Based Lead-free Piezoelectric Ceramics

李博森 廖忠新 高大强
材料研究学报2024,Vol.38Issue(1) :51-60.DOI:10.11901/1005.3093.2022.647

BNZ组分对KNN基无铅压电陶瓷结构和性能的影响

Effect of BNZ Component on Structure and Property of KNN Based Lead-free Piezoelectric Ceramics

李博森 1廖忠新 1高大强1
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作者信息

  • 1. 兰州大学物理科学与技术学院 兰州 730030
  • 折叠

摘要

制备铌酸钾钠-锆酸铋钠(1-x)K0.48Na0.52Nb0.96Sb0.04O3-x(Bi0.5Na05)ZrO3二元系无铅压电陶瓷并表征其结构和性能,研究了 BNZ组分对其结构和性能的影响.结果表明,这种系列压电陶瓷具有典型的钙钛矿结构.x=0.04的这种陶瓷最为致密,其相对密度为97.43%;压电性能最优:d33=463 pC/N、kp=0.55、Qm=37.这种陶瓷材料在室温下处于三方-四方(R-T)两相共存状态并具有纳米畴结构,使其压电性能优异.

Abstract

In order to promote the practical application of lead-free piezoelectric ceramics,in this pa-per,a kind of sodium potassium niobate-sodium bismuth zirconate(1-x)K048Na0.52Nb0.96Sb0.04O3-x(Bi0.5Na0.5)ZrO3 lead-free piezoelectric ceramics were prepared,and their crystallographic structure and perfor-mance were assessed.Results show that their relative dielectric constant and the resonant frequency temperature are stable(<10‰)with the variation of temperature;the piezoelectric ceramics are typical perovskite structure,and the most compact ceramic sample is obtained with x=0.04,which endows RD=97.43%,d33=463 pC/N,kp=0.55 and Qm=37;the piezoelectric ceramics consists of tripartite-tetragonal(R-T)two-phases and the existence of nanodomain structure may be the cause for the excellent piezo-electric properties of ceramic materials.

关键词

无机非金属材料/压电陶瓷/铌酸钾钠/纳米畴/温度稳定性

Key words

inorganic non-metallic materials/piezoelectric ceramics/potassium sodium niobate/nanometer domain/temperature stability

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基金项目

甘肃省教育科技创新青年博士基金(2022QB-002)

兰州大学奥迪威传感器有限公司联合研究院项目()

出版年

2024
材料研究学报
国家自然科学基金委员会 中国材料研究学会

材料研究学报

CSTPCD北大核心
影响因子:0.605
ISSN:1005-3093
参考文献量54
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