首页|BNZ组分对KNN基无铅压电陶瓷结构和性能的影响

BNZ组分对KNN基无铅压电陶瓷结构和性能的影响

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制备铌酸钾钠-锆酸铋钠(1-x)K0.48Na0.52Nb0.96Sb0.04O3-x(Bi0.5Na05)ZrO3二元系无铅压电陶瓷并表征其结构和性能,研究了 BNZ组分对其结构和性能的影响.结果表明,这种系列压电陶瓷具有典型的钙钛矿结构.x=0.04的这种陶瓷最为致密,其相对密度为97.43%;压电性能最优:d33=463 pC/N、kp=0.55、Qm=37.这种陶瓷材料在室温下处于三方-四方(R-T)两相共存状态并具有纳米畴结构,使其压电性能优异.
Effect of BNZ Component on Structure and Property of KNN Based Lead-free Piezoelectric Ceramics
In order to promote the practical application of lead-free piezoelectric ceramics,in this pa-per,a kind of sodium potassium niobate-sodium bismuth zirconate(1-x)K048Na0.52Nb0.96Sb0.04O3-x(Bi0.5Na0.5)ZrO3 lead-free piezoelectric ceramics were prepared,and their crystallographic structure and perfor-mance were assessed.Results show that their relative dielectric constant and the resonant frequency temperature are stable(<10‰)with the variation of temperature;the piezoelectric ceramics are typical perovskite structure,and the most compact ceramic sample is obtained with x=0.04,which endows RD=97.43%,d33=463 pC/N,kp=0.55 and Qm=37;the piezoelectric ceramics consists of tripartite-tetragonal(R-T)two-phases and the existence of nanodomain structure may be the cause for the excellent piezo-electric properties of ceramic materials.

inorganic non-metallic materialspiezoelectric ceramicspotassium sodium niobatenanometer domaintemperature stability

李博森、廖忠新、高大强

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兰州大学物理科学与技术学院 兰州 730030

无机非金属材料 压电陶瓷 铌酸钾钠 纳米畴 温度稳定性

甘肃省教育科技创新青年博士基金兰州大学奥迪威传感器有限公司联合研究院项目

2022QB-002

2024

材料研究学报
国家自然科学基金委员会 中国材料研究学会

材料研究学报

CSTPCD北大核心
影响因子:0.605
ISSN:1005-3093
年,卷(期):2024.38(1)
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