材料研究学报2024,Vol.38Issue(1) :61-70.DOI:10.11901/1005.3093.2023.158

碳纳米管/氧化锌协同增强碳纤维复合材料的电磁屏蔽性能

Synergistic Effect of Carbon Nanotubes with Zinc Oxide Nanowires for Enhanced Electromagnetic Shielding Performance of Hybrid Carbon Fiber/Epoxy Composites

马源 王函 倪忠强 张建岗 张若南 孙新阳 李处森 刘畅 曾尤
材料研究学报2024,Vol.38Issue(1) :61-70.DOI:10.11901/1005.3093.2023.158

碳纳米管/氧化锌协同增强碳纤维复合材料的电磁屏蔽性能

Synergistic Effect of Carbon Nanotubes with Zinc Oxide Nanowires for Enhanced Electromagnetic Shielding Performance of Hybrid Carbon Fiber/Epoxy Composites

马源 1王函 2倪忠强 1张建岗 1张若南 1孙新阳 1李处森 2刘畅 1曾尤1
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作者信息

  • 1. 中国科学院金属研究所沈阳材料科学国家研究中心 沈阳 110016;中国科学技术大学材料科学与工程学院 沈阳 110016
  • 2. 中国科学院金属研究所沈阳材料科学国家研究中心 沈阳 110016
  • 折叠

摘要

在碳纤维上原位生长氧化锌纳米线、沉积碳纳米管薄膜,经叠层铺设和真空辅助树脂浸渍成型制备出叠层混杂碳纤维/环氧树脂复合材料,表征其微观结构并系统地研究了这种材料的电导率和电磁屏蔽性能.结果表明,这种复合材料(厚度为2 mm)在8.2~12.4 GHz波段的电磁屏蔽效能达到50 dB,比碳纤维复合材料提高了 51.52%.这种材料的优异性能,可归因于氧化锌纳米线的高效介电损耗、连续碳纳米管薄膜的高导电性、层间多组元界面的多重反射和高效吸收损耗.

Abstract

Developing advanced composites with high electromagnetic shielding effectiveness is of great significance to ensure safety and reliability of electronic devices in complex electromagnetic envi-ronments.We proposed a novel strategy to fabricate carbon fiber-based hybrid composites by in-situ growing zinc oxide(ZnO)nanowires onto carbon fiber(CF)and subsequently depositing carbon nano-tubes(CNT),and infiltrating epoxy(EP)into laminated layers through vacuum-assisted resin transfer molding technique.Microstructures,electrical conductivity,and electromagnetic shielding performance of the acquired CNT-ZnO-CF/EP hybrid composites were investigated in detail.The hybrid composites of 2 mm thickness exhibited excellent electromagnetic shielding performance,and their total electromagnetic shielding effectiveness was up to 50 dB in the 8.2~12.4 GHz band,increasing by 51.52%in comparison to the CF/EP composites.Such high performance is mainly attributed to the high dielectric loss of ZnO nanowires,high electrical conductivity of continuous CNT films,and multiple reflection/absorption losses between laminated structures and multi-component interfaces.This work paves a way for development of advanced composites with high-efficiency electromagnetic shielding and structure/function integration.

关键词

复合材料/电磁屏蔽性能/叠层混杂结构/氧化锌纳米线/碳纳米管

Key words

composites/electromagnetic shielding performance/laminated hybrid structures/zinc ox-ide nanowires/carbon nanotubes

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基金项目

国家自然科学基金(52130209)

国家自然科学基金(51802317)

辽宁省自然科学基金(22-KF-12-04)

纳米功能复合材料山西省重点实验室开放基金(NFCM202102)

中国科学院金属所所创基金(2022-PY07)

沈阳材料科学国家研究中心项目(2022-FP35)

沈阳市科技计划项目(22-316-1-04)

出版年

2024
材料研究学报
国家自然科学基金委员会 中国材料研究学会

材料研究学报

CSTPCD北大核心
影响因子:0.605
ISSN:1005-3093
参考文献量43
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