材料研究学报2024,Vol.38Issue(2) :121-129.DOI:10.11901/1005.3093.2023.186

奥氏体化温度对含铜高碳马氏体不锈钢的组织和性能的影响

Effect of Austenitizing Temperature on Microstructure and Properties of High Carbon Cu-bearing Martensitic Stainless Steel

郝文俊 敬和民 席通 杨春光 杨柯
材料研究学报2024,Vol.38Issue(2) :121-129.DOI:10.11901/1005.3093.2023.186

奥氏体化温度对含铜高碳马氏体不锈钢的组织和性能的影响

Effect of Austenitizing Temperature on Microstructure and Properties of High Carbon Cu-bearing Martensitic Stainless Steel

郝文俊 1敬和民 1席通 2杨春光 2杨柯2
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作者信息

  • 1. 安徽工业大学材料科学与工程学院 马鞍山 243000
  • 2. 中国科学院金属研究所师昌绪先进材料创新中心 沈阳 110016
  • 折叠

摘要

使用光学显微镜(OM)、扫描电子显微镜(SEM)、X射线衍射(XRD)、电子背散射衍射(EBSD)和透射电子显微镜(TEM)等手段对高碳马氏体不锈钢进行表征,研究了添加铜(Cu)对其在不同奥氏体化温度下组织的变化,并分析了其强韧性和耐蚀性.结果表明:随着奥氏体化温度的升高合金中碳化物的含量降低,残余奥氏体的含量提高.Cu的添加促进了分布在基体上的小尺寸碳化物的析出,且使合金中残余奥氏体的含量显著提高.残余奥氏体的软化作用大于马氏体的强化作用,使含Cu高碳马氏体不锈钢的硬度稍有降低,但是其室温冲击功由8Cr18MoV的1.5J提高到8Cr18MoV-3.1Cu的9.1J,其韧性也大幅度提高.同时,残余奥氏体的增加使含Cu钢的自腐蚀电位有所降低.

Abstract

The effect of copper(Cu)addition on the microstructure,mechanical properties and corro-sion resistance of high carbon Cu-bearing martensitic stainless steels,being subjected to austenitizing treatment at different temperatures was investigated by means of optical microscopy(OM),scanning elec-tron microscope,(SEM),X-Ray diffraction(XRD),electron back scattered diffraction(EBSD)and trans-mission electron microscope(TEM).The results show that the fraction of carbides decreases and the con-tent of retained austenite increases gradually with the increase of austenitizing temperature.The addition of Cu has a positive effect on the amount of precipitation for small size carbides,which distributed in the matrix,and increases the retained austenite significantly.The hardness of high carbon Cu-bearing mar-tensitic stainless steel decreases slightly after Cu addition,because the softening effect of retained aus-tenite is greater than the strengthening effect of martensite.Meanwhile,the impact absorption energy in-crease from 1.5 J to 9.1 J,indicating that the toughness of the steel was enhanced significantly.Besides,the free-corrosion potential of the Cu-bearing stainless steels decreases due to the increase of retained austenite volume fraction.

关键词

金属材料/含铜高碳马氏体不锈钢/奥氏体化/硬度/耐蚀性/残余奥氏体

Key words

metallic materials/martensitic stainless steel/austenitizing temperature/hardness/corro-sion resistance/retained austenite

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基金项目

国家自然科学基金(52101293)

出版年

2024
材料研究学报
国家自然科学基金委员会 中国材料研究学会

材料研究学报

CSTPCDCSCD北大核心
影响因子:0.605
ISSN:1005-3093
参考文献量22
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