首页|GCr15轴承钢时效过程碳化物的演化行为

GCr15轴承钢时效过程碳化物的演化行为

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对GCr15轴承钢进行170℃时效处理,使用SEM、TEM、XRD等手段对其表征,研究了这种钢在时效过程中碳化物的演化行为及其对性能的影响.结果表明,在840℃淬火后再在230℃回火,钢的硬度不低于59 HRC,冲击韧性大幅度提高,钢中的残余奥氏体基本上消除,可保障其170℃的性能和尺寸稳定性.在时效过程中发生的碳原子配分和碳化物析出,使钢基体中碳的浓度、晶格畸变、微区应力应变先降低后稳定,过渡碳化物向非共格的渗碳体转变和粗化.这两个因素的耦合作用使钢的硬度降低、冲击韧性先升高后降低.马氏体的碳脱溶和碳化物类型的转变相互协调,使钢时效1000h到2000h间硬度有所回升.为了提高时效过程中钢的显微组织和性能的稳定性,淬火后又进行了深冷处理以引入高密度缺陷,促进了回火和时效过程中碳元素的配分,使析出的碳化物细小弥散并抑制了其在时效过程中的长大与粗化.深冷处理使碳化物的长大速率由298nm3/h降低到229.5 nm3/h,在一定程度上延缓了性能的衰退、提高了 GCr15轴承钢在真空干泵高温环境中的性能稳定性.
Carbide Evolution Behavior of GCr15 Bearing Steel During Aging Process
The evolution behavior of carbides in GCr15 bearing steel and its influence on the impact toughness during long-term aging at 170℃ have been investigated by means of SEM,TEM,and XRD,aiming to meet the requirements of vacuum dry pump bearings.The results demonstrate that after quenching at 840℃ and the tempering at 230℃,the hardness of GCr15 steel remains above 59 HRC with minimal retained austenite,which is favorable to the enhancement of performance and dimensional stability for the steel at 170℃.During the aging process,carbon atom partitioning and carbide precipita-tion lead to a decrease in carbon concentration,lattice distortion and micro-zone stress strain of the ma-trix,while transitional carbides precipitate,coarsen and then transform into non-coherent cementite.The resultant effect of these microstructural variation is a reduction in material hardness,while the impact toughness initially increasing and then decreasing.However,the cooperative effect of the decarboniza-tion of martensite and carbide type transformation makes hardness of steels remain stable or even in-crease a little in between 1000 h and 2000 h during the aging process.To improve the microstructure and performance stability during the aging process,cryogenic treatment was conducted after quenching.The introduction of high-density defects promotes effective carbon distribution during tempering and aging,which gives rise to uniform distribution and size control of fine carbides.Cryogenic treatment reduces the carbide growth rate from 298 nm3/h to 229.5 nm3/h,which delays the performance decline effectively and makes the GCr15 bearing steel satisfied with demands of vacuum dry pump bearings.

metallic materialsGCr15aging treatmentImpact toughnesscryogenic treatmentcar-bide evolution

刘震寰、李勇翰、刘洋、王培、李殿中

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中国科学院金属研究所沈阳材料科学国家研究中心 沈阳 110016

中国科学技术大学材料科学与工程学院 沈阳 110016

金属材料 GCr15钢 时效处理 冲击韧性 深冷处理 碳化物演变

中国科学院区域重点项目(A类)

KFJ-STS-QYZD-2021-20-002

2024

材料研究学报
国家自然科学基金委员会 中国材料研究学会

材料研究学报

CSTPCD北大核心
影响因子:0.605
ISSN:1005-3093
年,卷(期):2024.38(2)
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