材料研究学报2024,Vol.38Issue(4) :257-268.DOI:10.11901/1005.3093.2023.256

铝空气电池Ai-Zn-In-Mg-Ga-Mn合金阳极的电化学性能

Electrochemical Performance of Al-Zn-In-Mg-Ga-Mn Alloys as Anodes for Al-Air Batteries

吴厚燃 段体岗 马力 邵刚勤 张恒宇 张海兵
材料研究学报2024,Vol.38Issue(4) :257-268.DOI:10.11901/1005.3093.2023.256

铝空气电池Ai-Zn-In-Mg-Ga-Mn合金阳极的电化学性能

Electrochemical Performance of Al-Zn-In-Mg-Ga-Mn Alloys as Anodes for Al-Air Batteries

吴厚燃 1段体岗 2马力 2邵刚勤 3张恒宇 2张海兵2
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作者信息

  • 1. 武汉理工大学材料复合新技术国家重点实验室 武汉 430070;洛阳船舶材料研究所海洋腐蚀与防护全国重点实验室 青岛 266237
  • 2. 洛阳船舶材料研究所海洋腐蚀与防护全国重点实验室 青岛 266237
  • 3. 武汉理工大学材料复合新技术国家重点实验室 武汉 430070
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摘要

研究了铝空气电池的Al-Zn-In-Mg-Ga-Mn合金阳极在2 mol/L NaCl和4 mol/LKOH电解液中的自腐蚀行为和电化学性能.结果表明,在2 mol/L的NaCl和4 mol/L的KOH溶液中,Al-Zn-In-Mg-Ga-Mn合金阳极比纯A1阳极的腐蚀电位(Ecorr)分别负移了0.041和0.018 V,自腐蚀速率分别降低了0.2146和15.1 mg·cm-2·h-1,使金属阳极的电化学活性得以提高,自腐蚀行为受到了抑制.在2mol/L的NaCl电解液中,合金阳极的放电容量峰值达到2608.96 Ah·kg-1,比纯Al阳极提高了55.59%;能量密度最高为1742.61 Wh·kg-1,比纯Al阳极提高了274.58%,阳极效率为87.55%.在4 mol/L的KOH电解液中,合金阳极的放电容量最高为1605.15 Ah·kg-1,比纯Al阳极提高了131.27%;能量密度最高为1404.83 Wh·kg-1,比纯Al阳极提高了231.52%,阳极效率为53.86%.

Abstract

The free corrosion behavior and electrochemical properties of Al-Zn-In-Mg-Ga-Mn alloys,as anodes working with 2 mol/L NaCl and 4 mol/L KOH electrolytes were studied.Results revealed that in the two electrolytes,the corrosion potential(Ecorr)of alloy anodes shifted negatively by 0.041 V and 0.018 V,and the free corrosion rates decreased by 0.2146 and 15.1 mg·cm-2·h-1,respectively in the contrast to those of pure Al anode.The electrochemical activity of pure Al anode was improved,while its free corro-sion behavior was inhibited.In the 2 mol/L NaCl electrolyte,the discharge capacity peak of the alloy an-ode reached 2608.96 Ah·kg-1,which was 55.59%higher than that of the pure Al anode.The highest ener-gy density attained 1742.61 Wh·kg-1,being 274.58%superior to that of the pure Al anode.The anode effi-ciency was 87.55%.In the 4 mol/L KOH electrolyte,the highest discharge capacity of the Al-Zn-In-Mg-Ga-Mn alloy anode was 1605.15 Ah·kg-1,which was 131.27%higher than that of the pure Al anode.The high-est energy density was 1404.83 Wh·kg-1,which was 231.52%higher than that of the pure Al anode.The anode efficiency was 53.86%.

关键词

金属材料/A1-Zn-In-Mg-Ga-Mn合金/铝空气电池/电化学性能/腐蚀行为

Key words

metallic materials/Al-Zn-In-Mg-Ga-Mn alloy/aluminum-air battery/electrochemical per-formance/corrosion behavior

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基金项目

国家重点研发计划(2022YFB3808800)

出版年

2024
材料研究学报
国家自然科学基金委员会 中国材料研究学会

材料研究学报

CSTPCDCSCD北大核心
影响因子:0.605
ISSN:1005-3093
参考文献量48
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