材料研究学报2024,Vol.38Issue(8) :569-575.DOI:10.11901/1005.3093.2023.464

WO3/Pt和NiO电极电致变色器件的性能

Color-changing Performance of Electrochromic Devices Based on WO3/Pt-NiO Electrodes

郝子恒 郑刘梦晗 张妮 蒋恩桐 王国政 杨继凯
材料研究学报2024,Vol.38Issue(8) :569-575.DOI:10.11901/1005.3093.2023.464

WO3/Pt和NiO电极电致变色器件的性能

Color-changing Performance of Electrochromic Devices Based on WO3/Pt-NiO Electrodes

郝子恒 1郑刘梦晗 2张妮 1蒋恩桐 2王国政 2杨继凯2
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作者信息

  • 1. 微光夜视技术重点实验室 西安 710065
  • 2. 长春理工大学物理学院 长春 130022
  • 折叠

摘要

将水热法和电沉积相结合制备WO3/Pt复合薄膜并表征其组成、微结构和性能,将其作为阴极制做了WO3/Pt-NiO电致变色器件并测试其性能.结果表明,WO3/Pt-NiO电致变色器件具有较为迅速的时间响应(着色/褪色的为29.62/18.84 s)和适当的光调制范围(630 nm处为47%).这种WO3/Pt-NiO电致变色器件,具有大光调制、高着色效率和高开关速度等性能.

Abstract

The application of electrochromic devices(ECDs)in smart windows provides new solu-tions for energy conservation and environmental protection.WO3/Pt composite films for electrochromic cathodes were prepared through a combination of hydrothermal and electrodeposition methods.WO3/Pt composite films of different deposition times were characterized and their electrochromic properties were examined.Next,NiO thin films were prepared by electrodeposition as electrochromic anodes.WO3/Pt-NiO electrochromic devices were constructed with WO3/Pt composite films and NiO films as color changing cathodes and anodes,respectively.The WO3/Pt-NiO electrochromic device has a relatively fast response time(coloring/fading rate of 18.84/29.62 s)and a good optical modulation range(47% at 630 nm).Its de-signed ECD has the characteristics of large optical modulation,high coloring efficiency,and fast switching speed.These characteristics make WO3/Pt-NiO electrochromic devices a very promising candidate for smart windows in lighting control and energy-saving applications,and their use as color-changing smart windows has broad application prospects in fields such as architecture,aircraft,and automobiles.

关键词

复合材料/变色性能/电致变色/WO3/Pt复合薄膜

Key words

composites/color-change performance/electrochromism/WO3/Pt composite film

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基金项目

国家自然科学基金(51502023)

吉林省科技厅项目(20200201077JC)

吉林省教育厅项目(JJKH20210800KJ)

吉林省教育厅项目(JJKH20220726-KJ)

重庆自然科学基金(CSTB2022NSCQ-MSX0751)

出版年

2024
材料研究学报
国家自然科学基金委员会 中国材料研究学会

材料研究学报

CSTPCD北大核心
影响因子:0.605
ISSN:1005-3093
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