材料研究学报2024,Vol.38Issue(8) :614-620.DOI:10.11901/1005.3093.2023.521

B4C-Al2O3复合陶瓷的增韧机理

Toughening Mechanism of B4C-Al2O3 Composite Ceramics

张巍 张杰
材料研究学报2024,Vol.38Issue(8) :614-620.DOI:10.11901/1005.3093.2023.521

B4C-Al2O3复合陶瓷的增韧机理

Toughening Mechanism of B4C-Al2O3 Composite Ceramics

张巍 1张杰2
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作者信息

  • 1. 中国科学院金属研究所沈阳材料科学国家研究中心 沈阳 110016
  • 2. 中国科学院金属研究所沈阳材料科学国家研究中心 沈阳 110016;沈阳工业大学材料科学与工程学院 沈阳 110870
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摘要

在碳化硼(B4C)陶瓷中加入第二相Al2O3,研究其对B4C陶瓷断裂韧性的影响和B4C-Al2O3复合陶瓷的增韧机理.结果表明,在B4C陶瓷中引入第二相Al2O3使B4C陶瓷的断裂韧性提高.Al2O3加入量为40%(质量分数)的B4C-Al2O3复合陶瓷,其断裂韧性达到最大值4.96 MPa·m1/2.B4C-Al2O3复合陶瓷的增韧机理是,在B4C-Al2O3复合陶瓷中裂纹的扩展过程中Al2O3晶粒形成了解理结构.这种解理结构,延长了裂纹扩展的路径和消耗了部分裂纹扩展能.同时,Al2O3晶粒与B4C晶粒之间因热膨胀失配而产生了残余应力.虽然B4C晶粒内的压应力有利于抑制裂纹的扩展,但是B4C晶粒与Al2O3晶粒的相界处产生的张应力在一定程度上弱化相界的结合而使部分裂纹在扩展过程中沿晶扩展出现偏转,从而使B4C-Al2O3复合陶瓷的断裂韧性提高.

Abstract

B4C ceramics has extremely high hardness,but its fracture toughness is low.In order to improve the fracture toughness of B4C ceramics,the effect of introducing the second phase Al2O3 on the fracture toughness of B4C ceramics is studied,and the toughening mechanism of B4C-Al2O3 composite ce-ramics is explored.The results indicate that the addition of Al2O3 as the second phase can improve the fracture toughness of B4C ceramics.Among others,the fracture toughness of B4C-Al2O3 composite ceram-ics with 40% Al2O3 reaches a maximum value of 4.96 MPa·m1/2.The toughening mechanism of B4C-Al2O3 composite ceramics is that Al2O3 grains experience cleavage cracking during the crack propagation,in-creasing the path of crack propagation;thus,part of crack propagation energy is consumed.Meanwhile,residual stress is generated between Al2O3 grains and B4C grains due to their thermal expansion mis-match.On the one hand,the compressive stress inside B4C grains is beneficial for inhibiting crack propa-gation.On the other hand,the tensile stress generated at the phase boundary between B4C grains and Al2O3 grains weakens the bonding of the phase boundary to some extent,leading to some cracks propa-gating along the phase boundary during the propagation process;therefore,some cracks are deflected,and so the fracture toughness of B4C-Al2O3 composite ceramics is improved.

关键词

无机非金属材料/断裂韧性/B4C-Al2O3复合陶瓷/解理结构/热膨胀失配/裂纹扩展

Key words

inorganic non-metallic materials/fracture toughness/B4C-Al2O3 composite ceramics/cleavage structure/thermal expansion mismatch/crack propagation

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基金项目

辽宁省自然科学基金(2022-MS-013)

中国科学院金属研究所自主部署项目(E255L401)

沈阳材料科学国家研究中心青年人才项目(E21SL412)

出版年

2024
材料研究学报
国家自然科学基金委员会 中国材料研究学会

材料研究学报

CSTPCD北大核心
影响因子:0.605
ISSN:1005-3093
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