首页|水系双离子电池的研究进展与展望

水系双离子电池的研究进展与展望

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  • 国家科技期刊平台
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随着消费电子、电动汽车与规模储能产业的迅速发展,人们对电化学储能技术的安全高效提出了更高的要求.然而,锂离子电池(LIBs)存在的安全隐患问题制约了其在规模储能市场的应用.水系双离子电池(ADIBs)是一类以水系电解液作为离子传输介质且阴、阳离子均作为载流子同时参与电极电化学反应的新型储能技术,具有安全性能优异、功率密度高、绿色环保、性价比高等优势,在大规模储能领域具有潜在的应用前景.本综述从ADIBs的基本工作原理以及限制其发展的关键科学问题出发,归纳了近年来从电解液设计角度出发,拓宽电化学稳定电压窗口的几种常用方法,并总结了在正极和负极材料优化、储能机理研究方面取得的重要进展.最后,基于对ADIBs的理解,对其研究前景和未来研究方向进行了展望.本文将为水系储能电池研究的工作者提供参考,并为推动ADIBs的发展和促进高安全储能技术的进步发挥积极作用.
Research progress and perspectives of aqueous dual-ions batteries
With the rapid development of consumer electronics,electric vehicles,and large-scale energy storage industry,high requirements for the safety and efficiency of electrochemical energy storage technology.However,safety hazards associated with lithium-ion batteries limit their application in the energy storage market.Aqueous dual-ion batteries(ADIBs)have emerged as a new energy storage device that uses an aqueous electrolyte as the ion transport medium.In ADIBs,anions and cations in the electrolyte act as carriers,simultaneously participating in the electrode electrochemical reaction.ADIBs show potential application prospects in large-scale energy storage owing to their remarkable advantages,such as excellent safety performance,high power density,eco-friendliness,and high cost-effectiveness.This review delves into the working principle of ADIBs and addresses key scientific issues limiting their further development.The authors summarize various strategies to broaden the electrochemical stable voltage window,focusing on recent advances in electrolyte design.Then,the important progress made in optimizing cathode and anode materials and their energy storage mechanisms are elaborated.Finally,based on the knowledge and understanding of ADIBs,future research prospects and directions are proposed.Therefore,this study aims to provide a valuable reference for researchers in aqueous energy storage technology.This review contributes to promoting the development of ADIBs and accelerating progress in high-safety energy storage.

aqueousdual-ion batterieselectrolytescathode materialsanode materials

郭秀丽、周小龙、邹才能、唐永炳

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中国科学院深圳先进技术研究院,先进储能技术研究中心,广东 深圳 518055

中国石油深圳新能源研究院,广东 深圳 518118

水系 双离子电池 电解液 正极材料 负极材料

国家重点研发计划国家自然科学基金国家自然科学基金国家自然科学基金国家自然科学基金广东省自然科学基金广东省自然科学基金深圳市科技规划项目深圳市科技规划项目深圳市科技规划项目深圳市工程实验室基金中国科学院科技服务网络计划

2022YFB2402600522720545212510552061160484519723292022A15150113652019B1515120005JSGG20211108092801002JSGG20220831104004008GJHZ20220913142809019XMHT2022010600520201600200012

2024

10.19799/j.cnki.2095-4239.2023.0614

储能科学与技术
化学工业出版社

储能科学与技术

CSTPCD北大核心
影响因子：0.852
ISSN：2095-4239
年,卷(期)：2024.13(2)
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