首页|锂/氟化碳电池电解液的研究进展

锂/氟化碳电池电解液的研究进展

扫码查看
锂/氟化碳(Li/CFx)电池作为一种具有最高理论比容量(860 mAh/g)和能量密度(2180 Wh/kg)的一次电池,具有高安全性能、低自放电率、平稳的放电电压和环境友好等优点,广泛应用于医疗、军事、电子科技和航空航天等领域.电解液作为Li/CFx电池必不可缺的一部分,在正负极之间起到传递离子的作用,具有重要的研究意义.本文从Li/CFx电池的低温性能、倍率性能以及放电平台等方面综述了Li/CFx电池电解液的研究进展;重点阐述了电解液理化性质、界面浸润与相容、锂离子溶剂化结构、C—F键活化和LiF形成与溶解等因素对Li/CFx电池放电性能的影响;最后,对Li/CFx电池新型电解液的研究提出了思考与展望.
Research progress on electrolyte for Li/CFx battery
Li/CFx battery,a primary battery with the highest theoretical specific capacity and energy density,has the advantages of high safety performance,low self-discharge rate,stable discharge voltage,and eco-friendliness and is widely used in the medical,military,electronic technology,aerospace,and other fields.Electrolyte,an indispensable component of Li/CFx battery,plays a pivotal role in transferring ions between the anode and cathode;it has important research significance.In this review,we summarize the research progress on electrolytes for Li/CFx batteries,especially emphasizing the relationships between electrolyte factors,such as the physicochemical properties of electrolytes,interface wettability and compatibility,lithium-ion solvation structure,C—F bond activation,LiF formation,and dissolution,and the electrochemical performance of Li/CFx batteries,such as low-temperature performance,high-rate performance,and discharge voltage platform.Finally,future research directions for Li/CFx battery electrolytes are discussed.

electrochemistryLi/CFx batteryelectrolyteslow temperature performancehigh rate performance

卢俊杰、彭丹、倪文静、杨媛、汪靖伦

展开 >

湖南科技大学化学化工学院,理论有机化学与功能分子教育部重点实验室,湖南 湘潭 411201

电化学 锂/氟化碳电池 电解液 低温性能 倍率性能

湖南省普通高等学校青年骨干教师培养项目湖南省自然科学基金岳麓山工业创新中心项目

H221052024JJ802023YCII0108

2024

储能科学与技术
化学工业出版社

储能科学与技术

CSTPCD北大核心
影响因子:0.852
ISSN:2095-4239
年,卷(期):2024.13(5)
  • 51