首页|ZnO的绿色合成及光催化降解模拟废水研究

ZnO的绿色合成及光催化降解模拟废水研究

扫码查看
以甘露醇为模板剂,通过绿色合成途径,分别采用化学沉淀法和水热合成法制备ZnO.使用X-射线粉末衍射仪(XRD)和扫描电子显微镜(SEM)对样品的结构和形貌进行表征,用亚甲基蓝模拟工业废水中的有机污染物,对ZnO样品光催化降解模拟废水的性能进行研究.实验结果表明,2 种方法合成的样品均为分散程度较好的六方纤锌矿结构,ZnO样品微粒尺寸随甘露醇用量的增加而减小.通过化学沉淀法得到的ZnO样品表面呈蚕蛹状且内部中空,通过水热合成法得到的ZnO样品呈牡丹花状.以甘露醇为模板制得的ZnO样品均能有效降解亚甲基蓝,催化降解反应符合准一级反应动力学特征.
Green Synthesis of ZnO and Its Photocatalytic Degradation Performance of Simulated Wastewater
ZnO was prepared by chemical precipitation and hydrothermal synthesis using mannitol as template through green synthesis method.X-ray powder diffractometer(XRD)and scanning electron microscope(SEM)were used to characterize the structure and morphology of the samples.Methylene blue was used to simulate organic pollutants in industrial wastewater,and the performance of photocatalytic degradation of simulated wastewater was studied.The experimental results show that the samples synthesized by the two methods are well dispersed hexagon-al wurtzite structure,and the particle size of ZnO samples decreases with the increase of mannitol dosage.The ZnO samples obtained by chemical precipitation are cocoon shape with annular surface and hollow interior,while the ZnO samples obtained by hydrothermal synthesis are peony shape.The ZnO samples prepared with mannitol as the template can effectively degrade methylene blue,and the catalytic degradation reaction conforms to the kinetic char-acteristics of the quasi-first-order reaction.

mannitoltemplateZnOphotocatalytic degradationwaste water treatment

李红英、邓少帅、徐萏怩、王唯一、姚成立

展开 >

合肥师范学院 化学与制药工程学院, 合肥 230601

甘露醇 模板 氧化锌 光催化降解 废水处理

安徽省高等学校自然科学研究重点项目国家级大学生创新训练项目(2023)合肥师范学院横向课题研究项目

2022AH052139202314098030HXXM2022090

2024

重庆科技学院学报(自然科学版)
重庆科技学院

重庆科技学院学报(自然科学版)

影响因子:0.329
ISSN:1673-1980
年,卷(期):2024.26(1)
  • 7