首页|CNTs@Fe2O3材料的构筑及其对锂硫电池性能的影响

CNTs@Fe2O3材料的构筑及其对锂硫电池性能的影响

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锂硫电池作为一种新型锂电池,具有高能量密度和低成本等优势,但硫正极在循环过程中性能退化的问题仍有待解决.为此,制备了一种用Fe2O3修饰的碳纳米管(CNTs@Fe2O3)作为载硫体.碳纳米管独特的中空结构能够有效应对体积膨胀效应,同时,生长在碳纳米管表面的Fe2O3颗粒能够有效吸附多硫化锂,从而抑制多硫化锂的穿梭;碳纳米管的长程导电结构能够提高难溶性多硫化锂沉积后的正极导电性.
Construction of CNTs@Fe2O3 Materials and Their Effects on the Performance of Lithium Sulfur Batteries
Lithium sulfur batteries, as a new type of lithium battery, have advantages of high energy density and low cost, but the performance degradation of sulfur positive electrodes during cycling is still a problem to be solved. To this end, an Fe2O3 modified carbon nanotubes (CNTs@Fe2O3) were prepared as a sulfur carrier. The unique hol-low structure of carbon nanotubes can effectively cope with the volume expansion effect, while the Fe2O3 particles grown on the surface of carbon nanotubes can effectively adsorb lithium polysulfide and thus inhibit lithium polysul-fide shuttling, and the long-range conductive structure of the carbon nanotubes can improve the electrical conduc-tivity of the positive electrode after the deposition of insoluble lithium polysulfide.

lithium sulfur batterycarbon nanotubesFe2O3cathode materialsulfur carrier

胡章涛、望军、郑毅、杨森、张瀚

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重庆科技学院 冶金与材料工程学院,重庆 401331

锂硫电池 碳纳米管 氧化铁 正极材料 载硫体

国家自然科学基金青年基金重庆科技学院研究生创新计划

52107223YKJCX2220231

2024

重庆科技学院学报(自然科学版)
重庆科技学院

重庆科技学院学报(自然科学版)

影响因子:0.329
ISSN:1673-1980
年,卷(期):2024.26(2)
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