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高熵氧化物在催化领域的应用研究进展

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高熵催化策略作为一种重要的材料设计策略,得益于其四大核心效应,基于高熵催化策略设计的高熵材料具有独特的结构特性和功能定制特性,一般包括高熵合金、高熵氧化物、高熵碳化物、高熵氟化物和高熵硫化物等.其中,高熵氧化物因其复杂的组成和大晶格畸变产生了不同的原子分布和独特的结合位点,有利于提升催化效率.在此,着重介绍了高熵催化原理及高熵催化剂的设计原则,阐述了高熵氧化物在催化降解、产氧析氢、CO2 转化等方面的应用及催化性能调控机制的研究进展,并指出高熵氧化物催化剂亟待解决的问题和未来发展方向.
Advancements in the Application of High-Entropy Oxides in the Field of Catalysis
High entropy is an important material design strategy in the field of materials.Benefiting from its four core effects,high entropy materials based on high entropy strategy design have unique structural and functional cus-tomization characteristics,which includes high entropy alloys,high entropy oxides,high entropy fluorides and high entropy sulfides.High entropy oxides generate different atomic distributions and unique binding sites due to their complex composition and large lattice distortion,which is beneficial for improving catalytic efficiency.This article focuses on the principle of high entropy catalysis and the design principles of high entropy catalysts.It elaborates in detail on the application of high entropy oxides in catalytic degradation,oxygen and hydrogen production,CO2 con-version,and the advancement of catalytic performance control mechanisms.It also points out the urgent problems and future development directions of high entropy oxide catalysts.

high entropy oxidecatalysisdegradationgeneration of hydrogen and oxygenCO2 conversion

燕艳、饶泽平、杨雪、王振华、蔡苇

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重庆科技大学 材料与新能源学院,重庆 401331

高熵氧化物 催化 降解 产氧析氢 CO2转化

重庆市高校创新研究群体项目重庆市教育委员会科学技术研究项目重庆市研究生科研创新项目重庆科技大学研究生创新计划项目

CXQT19031KJQN202301501CYS240789YKJCX2320214

2024

重庆科技学院学报(自然科学版)
重庆科技学院

重庆科技学院学报(自然科学版)

影响因子:0.329
ISSN:1673-1980
年,卷(期):2024.26(4)
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