首页|噻唑化合物对铜在硫酸中的缓蚀行为研究

噻唑化合物对铜在硫酸中的缓蚀行为研究

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利用失重法、极化曲线和电化学阻抗谱等方法研究2,5-二巯基-1,3,4-噻唑(DMTD)对纯铜在0.5 M的硫酸中的缓蚀作用.通过失重法研究缓蚀效果,并以其实验数据探讨吸附模型;采用极化曲线和电化学阻抗图谱研究缓蚀剂性能及机理.失重结果表明四种实验温度下DMTD均可明显减缓纯铜在硫酸溶液中的腐蚀,DMTD分子吸附满足Langmuir等温线;电化学分析可知DMTD抑制纯铜阴阳极腐蚀反应;随着DMTD浓度的增大,吸附膜层缓蚀性能增强;表面形貌观察分别证实了DMTD的缓蚀作用.2,5-二巯基-1,3,4-噻唑(DMTD)可有效抑制纯铜在0.5 mol·L-1的硫酸中的腐蚀.
Inhibition Behavior of Thiazole Compounds on Copper in Sulfuric Acid
The corrosion inhibition behavior of 2,5-dimerhydryl-1,3,4-thiazole(DMTD)on pure copper in 0.5 M sulfuric acid was studied by weight loss method,polarization curve and electrochemical impedance spectroscopy.The effect of corrosion inhibition was studied by weight loss method,and the adsorption model was discussed based on the experimental data.The electrochemical method was adopted to study the proper-ties and mechanism of corrosion inhibitor.The weight loss results show that DMTD can significantly slow down the corrosion of pure copper in sulfuric acid solution at all four experimental temperatures,and the or-ganic molecular adsorption meets the Langmuir isotherm.Electrochemical analysis showed that DMTD inhib-ited anode and cathode corrosion reaction of pure copper.With the increase of DMTD concentration,the corro-sion inhibition performance of the adsorption film enhanced.The corrosion inhibition effect of DMTD was confirmed by surface morphology observation.2,5-dimercapto-1,3,4-thiazole(DMTD)can effectively inhibit the corrosion of pure copper in 0.5 M sulfuric acid.

pure coppersulfuric acidDMTDadsorptioncorrosion inhibition

陈文、林怡辰、张旗麟、黄德兴

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楚雄师范学院 资源环境与化学学院,云南 楚雄 675000

纯铜 硫酸 DMTD 吸附 缓蚀

云南省大学生创新创业训练计划(2022)

202211391054

2024

楚雄师范学院学报
楚雄师范学院

楚雄师范学院学报

影响因子:0.221
ISSN:1671-7406
年,卷(期):2024.39(3)
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