首页|碱处理对废旧涤纶织物/汉麻秆复合材料性能影响研究

碱处理对废旧涤纶织物/汉麻秆复合材料性能影响研究

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为解决汉麻秆粉末与疏水性聚合物基体间界面相容性差的问题,以8%(质量分数)NaOH溶液为改性剂对汉麻秆进行碱处理,再制备废旧涤纶织物/汉麻秆复合材料.通过力学性能测试,结合扫描电镜(SEM)、X射线衍射(XRD)、差示扫描量热(DSC)等技术手段,对复合材料性能进行研究.结果表明:对汉麻秆进行碱处理后,汉麻秆粉末表面被刻蚀,粗糙度增加,非纤维素成分溶解,与基体之间的结合力增大.相较未经碱处理制备的废旧涤纶织物/汉麻秆复合材料,碱处理制备的复合材料弯曲强度提升了 25.0%,内结合强度提升了29.7%;玻璃化转变温度和结晶温度分别由 71.2℃和 216.5℃上升至 79.1℃和 220.7℃,界面相容性得以改善;结晶度减小.
Study on effect of alkali treatment on properties of waste polyester fabric/hemp stalk composite material
In order to solve the problem of poor interfacial compatibility between hemp stalk powders and hydrophobic polymer matrix,the hemp stalks were alkalized with 8%(mass fraction)NaOH solution as modifier,and then the waste polyester fabric/hemp stalk composite material was prepared.The properties of composite materials were studied through mechanical property testing,combining with scanning electron microscopy(SEM),X-ray diffraction(XRD)and differential scanning calorimetry(DSC)technical means.The results showed that after alkali treatment of hemp stalks,the surface of hemp stalk powders was etched,the roughness increased,the non-cellulose component dissolved,and the binding force between powders and matrix increased.The bending strength of comparing with the waste polyester fabric/hemp stalk composites prepared without alkali treatment,the bending strength of the composite prepared with alkali treatment increased by 25.0%,and the internal bonding strength increased by 29.7%.The glass transition temperature and crystallization temperature increased from 71.2℃and 216.5℃to 79.1℃and 220.7℃,respectively.And the interfacial compatibility was improved.Crystallinity decreased.

waste polyester fabrichemp stalkalkali treatmentmechanical propertyinterfacial compatibility

卢梅婕、李飞、谢周强、王子涵、冯佳昕、张继心、牛梅

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太原理工大学 轻纺工程学院,山西 太原 030024

太原理工大学 新材料界面科学与工程教育部重点实验室,山西 太原 030024

废旧涤纶织物 汉麻秆 碱处理 力学性能 界面相容性

山西省回国留学人员科研项目山西浙大新材料与化工研究院项目山西省自然青年科学基金

2020-0522021SX-TD01320210302124200

2024

产业用纺织品
东华大学,全国产业用纺织品科技情报站

产业用纺织品

影响因子:0.309
ISSN:1004-7093
年,卷(期):2024.42(3)
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