首页|消防服外层面料酸碱阻隔性能提升研究

消防服外层面料酸碱阻隔性能提升研究

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采用浸轧法,分别利用含氟整理剂和无氟整理剂对消防服外层面料进行处理,探讨整理剂质量浓度、浸渍时间对织物润湿性和耐酸碱性的影响,并对处理工艺参数进行优化.结果表明:随着整理剂质量浓度和浸渍时间的增加,织物的润湿性能整体呈先增加后趋于平缓的趋势,优化的无氟整理剂质量浓度为80 g/L、浸渍时间为30 min;优化的含氟整理剂质量浓度为60 g/L,浸渍时间为45 min.在优化工艺参数条件下,经无氟整理剂处理后织物的水接触角最高达141.7°,碱接触角为142.5°,具备较好的抗润湿性和耐碱性;经含氟整理剂处理后织物的水接触角最高达155.4°,碱接触角为146.1°,酸、碱标准透过时间分为别8 min和17 min,防酸碱渗透性能明显提升,且效果优于无氟整理剂处理的织物.说明通过降低织物表面能构建超疏水表面,能够减少液态危化品对消防服外层面料的溶蚀、穿孔,提升酸碱阻隔性能.
Research on improving the acid-alkali barrier performance of outer fabric of firefighting suits
Using immersion rolling method,the outer fabrics of firefighting suits were treated with fluorinated and non fluorinated finishing agents.The effects of finishing agent mass concentration and immersion time on the wettability and acid-alkali resistance of fabrics were studied,and the process parameters were optimized.The results showed that as the mass concentration of finishing agent and immersion time increased,the wettability of fabrics showed an overall trend of first increasing and then tending to plateau.The optimized mass concentration of non fluorinated finishing agent was 80 g/L,and the immersion time was 30 minutes.The optimized mass concentration of fluorinated finishing agent was 60 g/L,and the immersion time was 45 minutes.Under optimized process parameters,the fabric treated with non fluorinated finishing agent had a maximum water contact angle of 141.7° and an alkali contact angle of 142.5°,which had good anti wetting and alkali resistance.The water contact angle of the fabric treated with fluorinated finishing agent could reach up to 155.4°,and the alkali contact angle was 146.1°.The acid and alkali standard penetration time was 8 min and 17 min,respectively.The anti acid and alkali penetration performance was significantly improved,and the effect was better than that of fabrics treated with non fluorinated finishing agents.By reducing the surface energy of fabrics and constructing super hydrophobic surfaces,it was possible to reduce the dissolution and perforation of liquid hazardous chemicals on the outer fabric of firefighting suits,and improve the acid-alkali barrier performance.

firefighting suithazardous chemicalacid-alkali barrierprotect

石佩玉、肖阳阳、孙冰冰、吴一兰、丁亦、王妮

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东华大学产业用纺织品教育部工程研究中心,上海 201620

东华大学纺织学院,上海 201620

河北省纤维材料技术创新中心,河北石家庄 050035

消防服 危化品 酸碱阻隔 防护

国家重点研发计划中央高校基本科研业务费专项资金资助东华大学国家大学生创新训练建设项目

2022YFC30061022232024G-06-01202310255044

2024

产业用纺织品
东华大学,全国产业用纺织品科技情报站

产业用纺织品

影响因子:0.309
ISSN:1004-7093
年,卷(期):2024.42(8)