首页|钠离子电池电解液溶剂化结构对SEI的影响

钠离子电池电解液溶剂化结构对SEI的影响

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在钠离子电池中电解液是关键组成部分,其内部的溶剂化结构对固体电解质界面(SEI)的形成和组成具有重要影响,并直接影响钠离子电池的电化学性能.文章探讨钠离子电池电解液中溶剂化结构对SEI性质和电池性能的影响机制,总结高浓度电解液溶剂化结构研究的相关成果,探讨溶剂浓度、种类及溶剂化结构对SEI的影响,阐述了电解液中阴阳离子、溶剂分子间作用与钠离子电池性能之间的构效关系.
Effects of Solvation Structure of Sodium Ion Battery Electrolytes on SEI
In SIBs,the electrolyte and the solvent structure significantly influence the formation and composition of the solid electrolyte interface(SEI),directly impacting the electrochemical performance of the SIBs.This review aims to explore in depth the mechanism by which the solvation structure in sodium ion battery electrolytes affects the SEI properties and battery performance.Through a summary of recent resear-ches on the solvation structure of high concentration electrolytes,the effects of solvent concentration,type,and solvation structure on SEI are explored.The structure-activity relationship between anions and ca-tions,solvent intermolecular interactions,and sodium ion battery performance in electrolytes are also elucidated.

sodiumion batteryaqueous electrolyteorganic electrolytesolid electrolyte interface(SEI)

周钰祥、沈海林、陈小卉

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常州工学院化工与材料学院,江苏 常州 213032

常州大学材料科学与工程学院,江苏 常州 213164

钠离子电池 水系电解液 有机类电解液 固体电解质界面

国家自然科学基金江苏省教育厅高等学校基础科学(自然科学)研究重大项目常州市科技支撑计划(国际科技合作)

2227201122KJA150001CZ20220022

2024

常州工学院学报
常州工学院

常州工学院学报

影响因子:0.274
ISSN:1671-0436
年,卷(期):2024.37(1)
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