东北大学学报(自然科学版)2024,Vol.45Issue(7) :967-973.DOI:10.12068/j.issn.1005-3026.2024.07.008

镁处理对TiN液析行为的影响

Effect of Magnesium Treatment on Liquid Precipitation Behavior of TiN

张永余 马崑 闵义 刘承军
东北大学学报(自然科学版)2024,Vol.45Issue(7) :967-973.DOI:10.12068/j.issn.1005-3026.2024.07.008

镁处理对TiN液析行为的影响

Effect of Magnesium Treatment on Liquid Precipitation Behavior of TiN

张永余 1马崑 1闵义 1刘承军1
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作者信息

  • 1. 东北大学 多金属共生矿生态化冶金教育部重点实验室,辽宁 沈阳 110819;东北大学 冶金学院,辽宁 沈阳 110819
  • 折叠

摘要

为研究镁处理对钛微合金钢在凝固过程中TiN液析行为的影响,采用真空感应炉冶炼了试验钢.利用SEM-EDS结合图像处理软件,分析铸坯径向不同位置处镁处理钢对比非镁处理钢中夹杂物的成分和尺寸变化,并用FactSage软件对夹杂物的形成和析出进行了计算.结果表明:钢中TiN夹杂均在凝固前沿的液相中生成.氮含量增加,凝固过程中TiN的析出温度升高和析出量增加,并对后续Ti4C2S2和MnS的析出产生影响.非镁处理条件下,铸坯1/4处和中心处TiN夹杂的平均粒径分别为2.48和2.11 μm,镁处理后,尺寸分别降为1.50,1.45 μm和1.48,1.38 μm,数密度也有所增大.添加微量Mg,MgO·Al2O3即可稳定存在于钢中并在钢液降温过程中成为TiN的凝固核心,促使TiN夹杂分布弥散,减少了大尺寸TiN的生成.

Abstract

To investigate the effect of magnesium on TiN liquid precipitation in titanium microalloyed steel,the steel was melted in a vacuum induction furnace.The changes in inclusion composition and size in magnesium-treated steel at different billet positions were analyzed by SEM-EDS and imaging software and were compared with untreated steel.FactSage software was used to calculate inclusion formation.The results revealed that TiN inclusions form in the liquid phase at the solidification front.Higher nitrogen content increases TiN precipitation temperature and amount,and affects Ti4C2S2 and MnS precipitation.Without magnesium treatment,the average sizes of TiN are 2.48 and 2.11 μm in the quarter and center of slab,respectively.After magnesium treatment,the sizes decrease to 1.50,1.45,1.48,and 1.38 μm,respectively,with increased number density.Traces of Mg enable the stable existence of MgO·Al2O3,serving as TiN solidification cores,aiding dispersion and reducing the formation of large-size TiN during steel cooling.

关键词

镁处理/钛微合金钢/TiN/析出/热力学

Key words

magnesium treatment/titanium microalloyed steel/TiN/precipitate/thermodynamics

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基金项目

国家自然科学基金资助项目(51974075)

出版年

2024
东北大学学报(自然科学版)
东北大学

东北大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.507
ISSN:1005-3026
参考文献量8
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