首页|三元动力锂离子电池低温容量失效分析

三元动力锂离子电池低温容量失效分析

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为探究动力锂离子电池的低温特性,对比制造工艺相同但低温性能差异较大(A组性能较好)的A、B两组三元动力锂离子电池在低温(-35℃)条件下的容量差异.建立"电池-材料"联动分析方法,从内部材料微观特征分析电池低温容量失效的原因.三元正极材料结构是影响电池低温容量的关键因素.与A组相比,B组电池的正极材料颗粒结构松散,经过低温放电后,颗粒表面出现裂纹,导致B组正极材料在低温放电过程中活性Li+损失、固体电解质相界面(SEI)膜阻抗增加、材料电导率差,继而导致低温容量失效.
Failure analysis of low-temperature capacity of ternary power Li-ion battery
In order to explore the low-temperature performance of power Li-ion battery,the capacity difference of two groups of A and B ternary power Li-ion batteries with the same manufacturing process but different low-temperature performance(the performance of group A is better)at low temperature(-35 ℃)is compared.A"battery-material"linkage analysis method is established to analyze the causes of low-temperature capacity failure of batteries from the microscopic characteristics of internal materials.The structure of ternary cathode material is the key factor affecting the low-temperature capacity of battery.Compared with group A,the cathode material particles of group B have looser particle-structure,cracks appeared on the surface of the particles after discharge,resulting in the loss of active Li+of the cathode materials of group B during the low-temperature discharge process,the increase of solid electrolyte interface(SEI)film impedance,the poor conductivity of the material,which leads to the failure of low-temperature capacity.

ternary power Li-ion batterylow temperaturecapacityfailure

梁宏毅、黎华玲、甘友毅、邵丹

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广汽本田汽车有限公司,广东广州 510700

广州能源检测研究院,广东省动力电池安全重点实验室,广东广州 511447

三元动力锂离子电池 低温 容量 失效

国家市场监督管理总局科技项目广东省市场监督管理局科技项目广州市科技计划广州市市场监督管理局科技项目

2020MK1272022CZ072022010113572022kj23

2024

电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
年,卷(期):2024.54(2)
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