首页|基于单频阻抗的锂离子电池热失控分级预警

基于单频阻抗的锂离子电池热失控分级预警

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潜在的热失控风险,特别是过充电,可能会引发锂离子电池的安全事故.以电化学阻抗谱(EIS)为基础,采用单频阻抗X1Hz和X400Hz实现电池内部阻抗的实时检测.在不同充电倍率、环境温度和健康状态下进行验证,特征阻抗表现出很好的稳定性.基于X1Hz和X400Hz的单频阻抗,提出一种热失控安全分级预警方法,并验证该方法的可靠性.该方法的最后一级预警可在热失控前5 min以上发出安全预警.
Thermal runaway graded warning of Li-ion battery based on single-frequency impedance
The potential risk of thermal runaway,especially overcharging,may lead to safety accidents of Li-ion battery.Based on electrochemical impedance spectroscopy(EIS),the real-time detection of internal battery impedance is achieved by employing single-frequency impedance at X1Hz and X400Hz.After validation under different charging rates,environmental temperatures and states of health,the characteristic impedance demonstrates remarkable stability.Utilizing single-frequency impedance at X1Hz and X400Hz,a thermal runaway safety classification and warning method is proposed,its reliability is verified.The final-stage warning of this method can issue a safety warning more than 5 min before thermal runaway.

Li-ion batteryelectrochemical impedance spectroscopy(EIS)single-frequency impedancethermal runawaygraded warning

田爱娜、潘壮壮、吴铁洲、姜久春

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湖北工业大学太阳能高效利用及储能运行控制湖北省重点实验室,湖北武汉 430068

锂离子电池 电化学阻抗谱(EIS) 单频阻抗 热失控 分级预警

国家自然科学基金湖北省自然科学基金创新群体项目湖北省教育厅科研项目

521772122023AFA033T2021005

2024

电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
年,卷(期):2024.54(2)
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