电池2024,Vol.54Issue(2) :213-216.DOI:10.19535/j.1001-1579.2024.02.015

涂胶隔膜对锂离子电池性能的影响

Effect of adhesive-coated separator on performance of Li-ion battery

刘中奎 陈峰
电池2024,Vol.54Issue(2) :213-216.DOI:10.19535/j.1001-1579.2024.02.015

涂胶隔膜对锂离子电池性能的影响

Effect of adhesive-coated separator on performance of Li-ion battery

刘中奎 1陈峰1
扫码查看

作者信息

  • 1. 合肥国轩电池有限公司,安徽合肥 230001
  • 折叠

摘要

以3 Ah软包装动力锂离子电池为研究对象,考察喷涂和辊涂水系涂胶(聚偏氟乙烯及其共聚物)隔膜对电池性能的影响.水系喷涂涂胶隔膜电池具有较低的分容内阻和脉冲充放电直流内阻(DCR).以不低于2.00C倍率在2.50~4.25 V充放电,与辊涂涂胶隔膜电池相比,喷涂涂胶隔膜电池的倍率充电恒流充入比高约1%,倍率放电容量比高约0.2%,-20 ℃放电容量与25℃的容量比低3%以上.25 ℃和45 ℃下循环1 000次,两种涂胶隔膜性能差异较小;在25 ℃循环超过1 000次,喷涂涂胶隔膜电池性能稍好,循环2 000次的容量保持率高约1.7%.

Abstract

The effect of spraying and roller coating water-based adhesive-coated(polyvinylidene fluoride and its copolymers)separator on the performance of 3 Ah pouch power Li-ion battery is investigated.The spraying water-based adhesive-coated separator battery has a lower capacitance internal resistance and pulse charge and discharge direct current resistance(DCR).When charging and discharging in 2.50-4.25 V at a rate of not less than 2.00 C,compared with the roller coating adhesive-coated separator battery,the rate charge constant current charging ratio of the spraying adhesive-coated separator battery is about 1%higher,the rate discharge capacity ratio is about 0.2%higher and the ratio of discharge capacity at-20 ℃ to the capacity at 25 ℃ is more than 3%lower.After 1 000 cycles at 25 ℃ and 45 ℃,there is little difference in the performance of the two adhesive-coated separators.After more than 1 000 cycles at 25 ℃,the performance of the spraying adhesive-coated separator battery is slightly better,the capacity retention rate is about 1.7%higher after 2 000 cycles.

关键词

涂胶隔膜/喷涂/辊涂/内阻/循环/锂离子电池/动力电池

Key words

adhesive-coated separator/spraying/roller coating/internal resistance/cycle/Li-ion battery/power battery

引用本文复制引用

出版年

2024
电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
参考文献量8
段落导航相关论文