电池2024,Vol.54Issue(2) :235-238.DOI:10.19535/j.1001-1579.2024.02.020

双氟磺酰亚胺锂添加量对电解液性能的影响

Effect of bis(fluorosulfonyl)imide addition on the performance of electrolyte

吴圣明 吕亮 周怡 郭营军
电池2024,Vol.54Issue(2) :235-238.DOI:10.19535/j.1001-1579.2024.02.020

双氟磺酰亚胺锂添加量对电解液性能的影响

Effect of bis(fluorosulfonyl)imide addition on the performance of electrolyte

吴圣明 1吕亮 1周怡 1郭营军1
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作者信息

  • 1. 湖州昆仑亿恩科电池材料有限公司,浙江湖州 313000
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摘要

添加双氟磺酰亚胺锂(LiFSI)可以改善电解液的导电性和稳定性,但是会腐蚀铝箔.调整电解液中LiFSI和六氟磷锂(LiPF6)的比例,研究LiFSI添加量对铝箔腐蚀和电池性能的影响.CV测试结果表明,随着LiFSI添加量的增加,电解液对铝箔的腐蚀效果增强,LiFSI质量分数为12.5%时,铝箔在25 ℃、45 ℃下,分别于3.5 V左右、3.8V左右开始发生腐蚀.循环性能测试结果表明,当LiFSI质量分数为6.0%、LiPF6质量分数为6.5%时,磷酸铁锂锂离子电池在2.50~3.65 V以0.5 C充电、1.0 C放电,25 ℃下循环3 500次的容量保持率为99.5%.

Abstract

The addition of bis(fluorosulfonyl)imide(LiFSI)can improve the conductivity and stability of electrolyte,but will corrode the aluminum foil.The effect of LiFSI content on corrosion of aluminum foil and the battery performance is studied by adjusting the ratio of LiFSI and lithium hexafluorophosphate(LiPF6)in the electrolyte.The CV test results show that with the increase of LiFSI content,the corrosion effect of the electrolyte on the aluminum foil is enhanced.When the mass fraction of LiFSI is 12.5%,the aluminum foil begin to corrode at about 3.5 V at 25 ℃ and about 3.8 V at 45 ℃.The cycle performance test results show that when the mass fraction of LiFSI and LiPF6 is 6.0%and 6.5%respectively,the lithium iron phosphate Li-ion battery is charged at 0.5 C and discharged at 1.0 C in 2.50-3.65 V,the capacity retention rate is 99.5%after 3 500 cycles at 25 ℃.

关键词

锂离子电池/铝箔/双氟磺酰亚胺锂(LiFSI)/六氟磷酸锂(LiPF6)/腐蚀/电解液

Key words

Li-ion battery/aluminum foil/bis(fluorosulfonyl)imide(LiFSI)/lithium hexafluorophosphate(LiPF6)/corrosion/electrolyte

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出版年

2024
电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
参考文献量5
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