首页|钠离子电池用O3型层状金属氧化物研究进展

钠离子电池用O3型层状金属氧化物研究进展

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O3型层状金属氧化物具有理论容量高、制备简单等优势,是有前景实现商业化应用的钠离子电池正极材料之一.固有的缺点严重限制了层状金属氧化物正极的商业化进程,迫切需要解决.系统总结不可逆相变、表面侵蚀、产气等问题,分析比较固相法、共沉淀法和溶胶凝胶法等3种常用合成方法的优缺点,对O3型层状金属氧化物相关改性策略进行归纳,包括元素掺杂、表面包覆、混相设计和高熵设计等.
Research progress in O3-type layered metal oxides for sodium-ion battery
Because of high theoretical capacity and simple preparation,O3-type layered metal oxides are considered as one of the promising cathode materials for sodium-ion battery.The inherent shortcomings of layered metal oxide cathode seriously limit its commercialization process and need to be solved urgently.Problems such as irreversible phase transformation,surface erosion,and gas production are systematically summarized.The advantages and disadvantages of three common synthesis methods including solid phase method,co-precipitation method and sol-gel method are analyzed and compared,and relevant modification strategies of O3-type layered metal oxides are summarized,including element doping,surface coating,multiphase design and high entropy design.

sodium-ion batteryO3-type layered metal oxideattenuation mechanismsynthesismodification strategycathode material

刘卓敏、孙旦、谌红玉、唐有根

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中南大学化学化工学院,湖南长沙 410083

湖南信达新材料有限公司,湖南长沙 410300

钠离子电池 O3型层状金属氧化物 衰减机制 合成 改性策略 正极材料

2024

电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
年,卷(期):2024.54(2)
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