电池2024,Vol.54Issue(3) :369-373.DOI:10.19535/j.1001-1579.2024.03.016

生物质碳-硅复合负极材料的电化学性能

Electrochemical performance of biomass carbon-silicon composite anode materials

张长安 杨丽杰 曹新龙 贾彦龙
电池2024,Vol.54Issue(3) :369-373.DOI:10.19535/j.1001-1579.2024.03.016

生物质碳-硅复合负极材料的电化学性能

Electrochemical performance of biomass carbon-silicon composite anode materials

张长安 1杨丽杰 1曹新龙 1贾彦龙1
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作者信息

  • 1. 西安陕煤泾久新能源科技有限公司,陕西 西安 713700
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摘要

生物质碳具有独特的孔结构,较大的层间距,可加速Li+在无定形碳中的扩散速度.采用纳米硅、沥青、生物质碳,通过喷雾造粒、高温热解法制备生物质碳-硅复合负极材料.通过XRD、SEM、表面分析研究材料的表面形貌特征;通过恒流充放电等实验研究电化学性能.该材料制备扣式电池的首次充电比容量达到 1 692.5 mAh/g,首次库仑效率为 90.7%.制备的 18650 型电池在 2.75~4.20 V循环,以 1.00 C循环 616 次的容量保持率为 91.44%;以 0.50 C充电、1.00 C放电循环447 次的容量保持率为 94.48%,高于沥青碳-硅复合材料的 84.90%和 91.98%,说明该材料的倍率性能较好.

Abstract

Biomass carbon has a unique pore structure and large interlayer space,which can accelerate the diffusion of Li+in amorphous carbon.Nano-silicon,pitch and biomass carbon are used to prepare biomass carbon-silicon composite anode materials by spray granulation and high-temperature pyrolysis.The surface morphology of materials is studied by XRD,SEM and surface analysis.The electrochemical performance is investigated by galvanostatic charge-discharge experiments.The initial specific charge capacity of the button cell prepared by this material is 1 692.5 mAh/g and the initial Coulombic efficiency is 90.7%.The prepared 18650 type battery cycles in 2.75-4.20 V,the capacity retention rate of 616 cycles at 1.00 C is 91.44%,447 cycles at 0.50 C charge and 1.00 C discharge is 94.48%,which are higher than 84.90%and 91.98%of asphalt carbon-silicon composite,indicating that the rate capability of the material is better.

关键词

锂离子电池/负极/硅-碳复合材料/生物质碳/沥青碳/电化学性能

Key words

Li-ion battery/anode/silicon-carbon composite/biomass carbon/pitch carbon/electrochemical performance

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出版年

2024
电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
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