首页|共价有机框架基锂硫电池隔膜的研究进展

共价有机框架基锂硫电池隔膜的研究进展

扫码查看
共价有机框架(COFs)具有比表面积高、结构明确、孔分布均匀和易于功能化等特点,是一种有前景的锂硫电池隔膜材料.总结COFs基隔膜的进展,主要包括COFs基隔膜在锂硫电池中的应用,强调COFs的多孔尺寸和高比表面积在抑制多硫化物穿梭效应和促进Li+传导方面的重要性,说明电荷中性COFs、离子型COFs及COFs基复合材料在提高锂硫电池可逆容量和循环稳定性方面的优越性.介绍COFs基隔膜面临的挑战,并对未来的发展方向进行展望.
Research progress in covalent organic framework-based lithium-sulfur battery separator
Covalent organic frameworks(COFs)are promising separator materials for lithium-sulfur battery due to their high specific surface area,well-defined structure,uniform pore distribution,and facile functionalization.The progress of COFs-based separators is summarized,with particular emphasis on the application of COFs-based separators in lithium-sulfur batteries and the importance of the porous size and high specific surface area of COFs in inhibiting the polysulfide shuttle effect and promotion of Li+conduction.The advantages of charge-neutral COFs,ionic COFs and COFs-based composites in improving the reversible capacity and cycle stability of lithium-sulfur batteries are explained.The challenges faced by COFs-based separators are presented and the future development direction is provided.

lithium-sulfur batterycovalent organic frameworks(COFs)functionalized separator modificationlithium polysulfideshuttle effect

沈彬彬、李涛

展开 >

湖北文理学院理工学院机械与汽车工程学院,湖北 襄阳 441025

锂硫电池 共价有机框架(COFs) 功能化隔膜改性 多硫化锂 穿梭效应

襄阳市"汉江智库"一般课题湖北文理学院理工学院课题

HJZKYBKT202301242022JYYB09

2024

电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
年,卷(期):2024.54(3)