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SOC对锂离子电池存储性能影响及K值筛选工艺

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锂离子电池荷电状态(SOC)和老化工艺对电池的存储性能以及模组电池的制备和性能具有重要影响.研究SOC对磷酸铁锂锂离子电池存储性能的影响.高温(60℃)长时间存储时,随着SOC降低,电池的产气变严重,负极上发生的副反应是产气的主要来源.在30%SOC下,电池处于产气较少的理想存储状态.在30%SOC下,通过调整45℃高温和常温老化时间对K值筛选工艺进行优化.高温老化有利于区分不同自放电速率的电池.模组充放电一致性测试表明,随高温老化时间的延长,模组充放电压差减小,电池一致性提高.实验结果为磷酸铁锂锂离子电池长期储存、运输和制备提供参考.
Influence of SOC on the storage performance of Li-ion battery and the screening process of K value
The state of charge (SOC) and aging process of Li-ion battery have important influence on the storage performance of the battery,and the preparation and performance of the module.The influence of the SOC on the storage performance of lithium iron phosphate Li-ion battery is studied.When the battery is stored at high temperature (60 ℃) for a long time,the gas production of the battery becomes serious with the decrease of the SOC,the side reaction on the anode is the main source of gas production.At 30% SOC,the battery can be in an ideal storage state with less gas production.At 30% SOC,the K-value screening process is optimized by adjusting the aging time at 45 ℃ and room temperature.High-temperature aging is beneficial to distinguish cells with different self-discharge rates.The charge-discharge consistency test shows that the charge-discharge voltage difference of the module decreases and the consistency of the battery increases with the increase of high-temperature aging time.The experimental results provide a reference solution for the long-term storage,transportation and preparation of lithium iron phosphate Li-ion battery.

lithium iron phosphateLi-ion batterystate of charge (SOC)high temperature agingmodule

许汉良、陈仁鹏、伍斌、南俊民

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珠海鹏辉能源有限公司,广东珠海 519199

华南师范大学化学学院,广东广州 510006

磷酸铁锂 锂离子电池 荷电状态(SOC) 高温老化 模组

2024

电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
年,卷(期):2024.54(4)