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全固态锂离子电池用硫化物电解质研究进展

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全固态锂离子电池用硫化物电解质体系具有离子导电率高、制备方法简易、延展性良好和电化学性能稳定等优点,但距离大规模应用仍有一定难度.综述全固态锂离子电池硫化物电解质的研究现状,介绍包含玻璃态、玻璃陶瓷态和晶态等类型的电解质种类,列举硫化物固态电解质的常见制备方法,总结现有的正极与电解质界面、负极与电解质界面以及电解质自身稳定性等问题及相关解决方案.对硫化物电解质在全固态锂离子电池的应用前景作出展望.
Research progress in sulfide electrolytes for all-solid-state Li-ion battery
The sulfide electrolyte system for all-solid-state Li-ion battery has advantages of high ionic conductivity,simple preparation method,good ductility,and stable electrochemical performance.However,it is still difficult to apply on a large scale.The research of sulfide-based electrolyte for all-solid-state Li-ion battery is reviewed.The type of electrolytes including glass,glass ceramic and crystal is introduced,the common preparation methods of sulfide solid electrolytes are listed,the existing problems of cathode-electrolyte interface,anode-electrolyte interface and electrolyte stability are summarized and the relevant solutions are also provided.The application of sulfide electrolyte in all-solid-state Li-ion battery is prospected.

Li-ion batteryall-solid-state batteryelectrolytesulfide electrolyteprepare methodelectrode-electrolyte interfaceelectrolyte stability

郭邦军、贾理男、朱金辉、张希

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上海交通大学机械与动力工程学院,上海 200240

上海屹锂新能源科技有限公司,上海 201419

上海交通大学化学化工学院,上海 200240

锂离子电池 全固态电池 电解质 硫化物电解质 制备方法 电解质/电极界面 电解质稳定性

国家自然科学基金国家自然科学基金

5217721852007119

2024

电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
年,卷(期):2024.54(4)