首页|复配人造石墨比例对电化学性能的影响

复配人造石墨比例对电化学性能的影响

扫码查看
为探究人造石墨二次颗粒和单颗粒的最佳混合比例以及对电化学性能的影响,利用SEM、XRD对复配石墨进行形貌及微观结构分析,对负极人造石墨二次颗粒及单颗粒不同配方质量比(3∶7、5∶5和 7∶3)进行验证,参考国标GB/T 36276-2018,对比倍率、高低温、存储自放电及循环性能等电化学性能.25℃下 2.0 P(800 W)放电容量、5℃低温能量保持率、25℃自放电、25℃下0.5 P及1.0 P循环性能在二次颗粒与单颗粒复配质量比为5∶5时表现最优.常温以0.5 P在2.50~3.65 V循环 1 459 次,能量保持率为 95.2%,以 1.0 P在 2.50~3.65 V循环 2 500 次,能量保持率为 88.7%.
Effect of secondary mixing artificial graphite ratios on electrochemical performance
To investigate the optimal mixing ratio of secondary and single particle artificial graphite and their effect on electrochemical performance,the morphology and microstructure of the compound graphite are characterized and analyzed by SEM and XRD.The different formula mass ratios(3∶7,5∶5 and 7∶3)of secondary particles and single particles of artificial graphite for anode are verified.The electrochemical performance characteristics such as rate capability,high and low temperature,storage self-discharge and cycle performance are compared with the national standard GB/T 36276-2018.2.00 P(800 W)discharge capacity at 25℃,5℃low-temperature energy retention rate,self-discharge at 25℃,0.5 P and 1.0 P cycle performance at 25℃is the best when the mass ratio of secondary particles to single particles is 5∶5,the room temperature energy retention rate of 1 459 cycles at 0.5 P in 2.50-3.65 V is 95.2%,the energy retention rate of 2 500 cycles at 1.0 P in 2.50-3.65 V is 88.7%.

single particlesecondary particlesecondary mixing artificial graphiteelectrochemical performance

王盈来、张欣瑞、李艳红、方玲

展开 >

杭州南都动力科技有限公司,浙江 杭州 310000

单颗粒 二次颗粒 复配人造石墨 电化学性能

2024

电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
年,卷(期):2024.54(5)