首页|LaFeO3基SOFC阴极改性的研究进展

LaFeO3基SOFC阴极改性的研究进展

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作为固体氧化物燃料电池(SOFC)的重要组成部分,阴极性能的优劣影响电池的工作效率.钙钛矿型LaFeO3 基半导体材料具有特殊的电子-离子混合导电性质,是一种潜在的SOFC阴极材料.综述提高阴极材料性能的策略,按掺杂位置,介绍在LaFeO3 的A、B位单独掺杂和共掺杂时,采用的掺杂元素和掺杂量,并介绍纳米化、A位缺陷等修饰手段.分析改性对材料热膨胀系数、极化电阻、电化学效率和氧还原反应等性能的影响.
Research progress in modification of cathode for LaFeO3-based SOFC
As a crucial component of solid oxide fuel cell(SOFC),the performance of the cathode impacts the efficiency of the cell.Perovskite-type LaFeO3-based semiconductor materials are potential SOFC cathode materials due to unique mixed electronic-ionic conductive properties.The strategies to improve the performance of cathode materials are reviewed.According to the doping position,the doping elements and doping amounts used in separate and co-doping of the A-and B-site of LaFeO3 are introduced,as well as modification methods such as nanomaterialization,A-site defects.The effect of modification on the thermal expansion coefficient,polarization resistance,electrochemical efficiency and oxygen reduction reaction performance of the material is analyzed.

solid oxide fuel cell(SOFC)cathodeperovskiteelectrochemical performance

李辰雪、李刘帅、殷佳辉、杨浪、朱兵

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贵州大学电气工程学院,贵州 贵阳 550025

固体氧化物燃料电池(SOFC) 阴极 钙钛矿 电化学性能

贵州省科技支撑计划项目

2017YFB0902100

2024

电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
年,卷(期):2024.54(5)