电池2024,Vol.54Issue(5) :719-724.DOI:10.19535/j.1001-1579.2024.05.024

LaFeO3基SOFC阴极改性的研究进展

Research progress in modification of cathode for LaFeO3-based SOFC

李辰雪 李刘帅 殷佳辉 杨浪 朱兵
电池2024,Vol.54Issue(5) :719-724.DOI:10.19535/j.1001-1579.2024.05.024

LaFeO3基SOFC阴极改性的研究进展

Research progress in modification of cathode for LaFeO3-based SOFC

李辰雪 1李刘帅 1殷佳辉 1杨浪 1朱兵1
扫码查看

作者信息

  • 1. 贵州大学电气工程学院,贵州 贵阳 550025
  • 折叠

摘要

作为固体氧化物燃料电池(SOFC)的重要组成部分,阴极性能的优劣影响电池的工作效率.钙钛矿型LaFeO3 基半导体材料具有特殊的电子-离子混合导电性质,是一种潜在的SOFC阴极材料.综述提高阴极材料性能的策略,按掺杂位置,介绍在LaFeO3 的A、B位单独掺杂和共掺杂时,采用的掺杂元素和掺杂量,并介绍纳米化、A位缺陷等修饰手段.分析改性对材料热膨胀系数、极化电阻、电化学效率和氧还原反应等性能的影响.

Abstract

As a crucial component of solid oxide fuel cell(SOFC),the performance of the cathode impacts the efficiency of the cell.Perovskite-type LaFeO3-based semiconductor materials are potential SOFC cathode materials due to unique mixed electronic-ionic conductive properties.The strategies to improve the performance of cathode materials are reviewed.According to the doping position,the doping elements and doping amounts used in separate and co-doping of the A-and B-site of LaFeO3 are introduced,as well as modification methods such as nanomaterialization,A-site defects.The effect of modification on the thermal expansion coefficient,polarization resistance,electrochemical efficiency and oxygen reduction reaction performance of the material is analyzed.

关键词

固体氧化物燃料电池(SOFC)/阴极/钙钛矿/电化学性能

Key words

solid oxide fuel cell(SOFC)/cathode/perovskite/electrochemical performance

引用本文复制引用

基金项目

贵州省科技支撑计划项目(2017YFB0902100)

出版年

2024
电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
段落导航相关论文