首页|水系锌离子电池锰基正极材料研究进展

水系锌离子电池锰基正极材料研究进展

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可充电水系锌离子电池由于低成本和高安全性,被认为是储能设备的理想候选者.近年来,锰基正极材料由于低成本、低毒性、高工作电压、价态丰富和晶体结构多变等特点,得到广泛研究.锰基材料在循环过程中因结构坍塌引起的容量衰减,阻碍了水系锌离子电池的进一步发展.综述锰基正极材料的研究进展,包括各种锰基氧化物(MnO2、Mn2O3、Mn3O4和MnO等)及其储锌机理.归纳提高锰基正极材料电化学性能的优化策略,并展望锰基正极材料未来的发展.
Research progress in manganese-based cathode material for aqueous zinc-ion battery
Rechargeable aqueous zinc-ion battery is considered to be ideal candidates for energy storage devices due to their low cost and high safety.In recent years,manganese-based materials have been widely investigated because of their low cost,low toxicity,high operating voltage,multi-valence states and various crystal structures.The capacity decay caused by structural collapse during cycling has hindered the further development of manganese-based cathodes.The research progress in manganese-based cathode materials,including various manganese-based oxides(MnO2,Mn2 O3,Mn3 O4 and MnO)and their zinc storage mechanisms is reviewed.The optimization strategies for improving the electrochemical performance of manganese-based cathode materials are summarized,the future development of manganese-based cathode materials is prospected.

rechargeable batteryzinc-ion batterycathode materialmanganese-based materialzinc storage mechanism

徐淳、张姗、陈婷、黄明刚、李国春

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四川化工职业技术学院应用化工学院,四川 泸州 646300

江苏大学能源研究院,江苏 镇江 212013

二次电池 锌离子电池 正极材料 锰基材料 储锌机理

精细化工应用技术泸州市重点实验室开放课题

HYJH-2302-A

2024

电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
年,卷(期):2024.54(5)