金属有机框架基磷酸盐系正极材料研究进展
Research progress in metal-organic framework-based phosphate-based cathode material
何志宏 1宋焕巧 1罗明生1
作者信息
- 1. 北京石油化工学院新材料与化工学院,北京 102617;燃料清洁化及高效催化减排技术北京市重点实验室,北京 102617
- 折叠
摘要
磷酸盐系锂离子电池正极材料因导电性差和Li+扩散系数低等原因,发展受到限制.金属有机骨架(MOF)具有比表面积大、活性位点丰富等优点.通过MOF前驱体来提升磷酸盐系正极材料电化学性能有很高的可行性.从用MOF或MOF衍生物通过制备、掺杂和表面改性等 3 种不同方法改性正极材料的角度,综述近年来MOF基磷酸盐系锂离子电池正极材料的研究进展,并对MOF应用于锂离子电池正极材料的发展方向进行展望.
Abstract
The development of phosphate-based Li-ion battery cathode materials has been limited by factors such as poor electrical conductivity and low Li+diffusion coefficient.Metal-organic framework(MOF)offers advantages such as a large specific surface area and rich active sites.MOF precursor shows great potential for enhancing the electrochemical performance of phosphate-based cathode materials.The research progress in MOF-based phosphate-based Li-ion battery cathode materials in recent years is reviewed from the perspective of using MOF or MOF derivatives to modify cathode materials by three different methods:preparation,doping and surface modification.The development direction of MOF application in cathode materials for Li-ion battery is also prospected.
关键词
锂离子电池/正极材料/金属有机框架(MOF)/磷酸铁锂/导电性Key words
Li-ion battery/cathode material/metal-organic framework(MOF)/lithium iron phosphate/conductivity引用本文复制引用
出版年
2024
国家科技期刊平台
NSTL
万方数据