首页|钠离子电池聚阴离子型正极材料的不足与改进

钠离子电池聚阴离子型正极材料的不足与改进

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钠离子电池因钠资源丰富带来的低成本优势,成为锂离子电池潜在的替代方案.聚阴离子化合物作为一种钠离子电池正极材料,凭借结构多样性、高工作电压和高结构稳定性等特点,成为储能电极材料领域的研究热点.基于钠离子电池的工作原理以及材料结构与性能的关系,对正磷酸盐、焦磷酸盐、硫酸盐、氟磷酸盐和混合磷酸盐等聚阴离子正极材料的研究进展进行综述,指出各类材料的不足,并给出可行的改进手段.
Deficiency and modification of polyanionic cathode materials for sodium-ion battery
Sodium-ion battery has emerged as potential alternative to Li-ion battery due to their cost-effectiveness stemming from abundant sodium resources.Polyanionic compounds serve as cathode materials for sodium-ion battery,emerging as a hot research topic of electrode materials for energy storage owing to their structural diversity,high operating voltage and structural stability.Based on the working principle of sodium-ion battery and the relation between material structure and performance,the research progress in polyanionic cathode materials such as orthophosphates,pyrophosphates,sulfates,fluorophosphates and mixed phosphates is summarized.Furthermore,the deficiencies of materials are pointed out,the feasible improvement methods are given.

sodium-ion batterypolyanionic compoundcathode materialelectrochemical performancemodification

谢伟超、吴剑超、唐朝辉、朱贤徐、张喻升、李加兴

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雪天盐业集团股份有限公司,湖南 长沙 410114

湖南美特新材料科技有限公司,湖南 长沙 410200

湖南省井矿盐工程技术研究中心,湖南 长沙 410114

钠离子电池 聚阴离子化合物 正极材料 电化学性能 改性

2024

电池
全国电池工业信息中心 湖南轻工研究院

电池

CSTPCD北大核心
影响因子:0.336
ISSN:1001-1579
年,卷(期):2024.54(6)