首页|微量石墨烯包覆对LiNi0.8Co0.1Mn0.1O2电化学性能的影响

微量石墨烯包覆对LiNi0.8Co0.1Mn0.1O2电化学性能的影响

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使用 Hummers法得到氧化石墨烯,再通过还原氧化石墨烯制备石墨烯.使用高温固相法制备LiNi0.8 Co0.1 Mn0.1 O2 正极材料,将石墨烯加入乙醇溶液中,与增稠分散剂羧甲基纤维素钠(CMC)混合得到石墨烯溶液.利用液相自聚集法将石墨烯溶液微量包覆在 LiNi0.8 Co0.1 Mn0.1 O2表面.通过SEM、XRD以及电化学测试系统对石墨烯/LiNi0.8 Co0.1 Mn0.1 O2 复合材料进行表征和测试.结果表明,0.8%-石墨烯/LiNi0.8 Co0.1 Mn0.1 O2 复合材料性能最佳,首次充电比容量最大值达到 222.85 mAh/g,首次充放电比容量最大值达到 208.93 mAh/g,库仑效率为 93.75%.
Effect of trace graphene coating on the electrochemical performance of LiNi0.8Co0.1Mn0.1O2
Graphene oxide(GO)was obtained by Hummers method and then prepared by reducing GO.LiNi0.8 Co0.1 Mn0.1 O2 cathode material was prepared by high temperature solid phase method.Graphene was added to ethanol solution and then mixed with the thickening dispersant sodium carboxymethyl cellulose(CMC)to obtain graphene solution.The surface of LiNi0.8 Co0.1 Mn0.1 O2 was coated with graphene solution by liquid phase self-aggregation method.Graphene/LiNi0.8 Co0.1 Mn0.1 O2 composites were characterized and tested by SEM,XRD and electrochemical testing systems.The results show that 0.8%-graphene/LiNi0.8 Co0.1 Mn0.1 O2 composites have the best performance.The maximum initial charge-discharge capacity reaches 222.85 mAh/g and 208.93mA/g,and the coulomb efficiency is 93.75%.

grapheneLiNi0.8Co0.1Mn0.1O2trace coatingelectrochemical performance

刘雷斌、张淑娴、刘炫漓、李玲、邓凌峰

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中南林业科技大学材料科学与工程学院,长沙 湖南 410004

中南林业科技大学材料表面科学与技术湖南省重点实验室,长沙 湖南 410004

石墨烯 LiNi0.8Co0.1Mn0.1O2 微量包覆 电化学性能

国家自然科学基金重点资助项目

3153009

2024

电池工业
中国电池工业协会,轻工业化学电源研究所

电池工业

影响因子:0.287
ISSN:1008-7923
年,卷(期):2024.28(2)
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